Parallel and Combinatorial Liquid-Phase Synthesis of Alkylbiphenyls Using Pentaerythritol Support
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Wang-Kyu | - |
dc.contributor.author | Jang, Jong-Hoon | - |
dc.contributor.author | Jo, Hyunjong | - |
dc.contributor.author | Park, Kwangyong | - |
dc.date.available | 2019-03-08T21:58:53Z | - |
dc.date.issued | 2014-05 | - |
dc.identifier.issn | 2156-8952 | - |
dc.identifier.issn | 2156-8944 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/12273 | - |
dc.description.abstract | Unfunctionalized alkylbiphenyls were fabricated by a parallel and combinatorial synthesis using pentaerythritol as a tetrapodal soluble support for a sulfonate-based traceless multifunctional linker system. Nickel N-heterocyclic carbenecatalyzed reactions of pentaerythritol tetrakis(biphenylsulfonate)s with primary alkylmagnesium bromides generated the allcylbiphenyl derivatives by desulfitative cleavage/cross-coupling of the C S bond without any "memory" of the attachment on the support. Though the reactions were completed with sufficient yields in 12 h at room temperature, even with only 1.5 equiv of nucleophiles, they still retained the benefits of facile isolation observed in polymer-supported reactions. | - |
dc.format.extent | 7 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Parallel and Combinatorial Liquid-Phase Synthesis of Alkylbiphenyls Using Pentaerythritol Support | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/co400136k | - |
dc.identifier.bibliographicCitation | ACS COMBINATORIAL SCIENCE, v.16, no.5, pp 225 - 231 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000335940000005 | - |
dc.identifier.scopusid | 2-s2.0-84900453986 | - |
dc.citation.endPage | 231 | - |
dc.citation.number | 5 | - |
dc.citation.startPage | 225 | - |
dc.citation.title | ACS COMBINATORIAL SCIENCE | - |
dc.citation.volume | 16 | - |
dc.type.docType | Article | - |
dc.publisher.location | 미국 | - |
dc.subject.keywordAuthor | pentaerythritol | - |
dc.subject.keywordAuthor | traceless linker | - |
dc.subject.keywordAuthor | multifunctional cleavage | - |
dc.subject.keywordAuthor | combinatorial synthesis | - |
dc.subject.keywordPlus | ARYL GRIGNARD-REAGENTS | - |
dc.subject.keywordPlus | ORGANIC-SYNTHESIS | - |
dc.subject.keywordPlus | SOLUBLE SUPPORTS | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | LIBRARIES | - |
dc.subject.keywordPlus | TRACELESS | - |
dc.subject.keywordPlus | MOLECULES | - |
dc.subject.keywordPlus | METHODOLOGIES | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | GENERATION | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Pharmacology & Pharmacy | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Applied | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Medicinal | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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