Preparation and characterization of single crystals of tetrakis(4-(5,5-dimethyl-2-phenyl-1,3-dioxan-2-yl)phenyl)germane
DC Field | Value | Language |
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dc.contributor.author | Lee, Tae Won | - |
dc.contributor.author | Lee, Dong Woo | - |
dc.contributor.author | Choi, Yeonjeong | - |
dc.contributor.author | Ok, Kang Min | - |
dc.contributor.author | Park, Kwangyong | - |
dc.date.available | 2019-05-28T01:40:03Z | - |
dc.date.issued | 2019-01 | - |
dc.identifier.issn | 1226-086X | - |
dc.identifier.issn | 1876-794X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/18311 | - |
dc.description.abstract | A novel tetrakis(4-(5,5-dimethyl-2-phenyl-1,3-dioxan-2-yl)phenyl)germane (2) was synthesized by the reaction of germanium(IV) tetrachloride with 4-(5,5-dimethyl-2-phenyl-1,3-dioxan-2-yl)phenyllithium. Colorless plate-shaped single crystals obtained from recrystallization in ether were characterized by the single-crystal X-ray diffraction. The organogermanium compound was crystallized in a noncentrosymmetric nonpolar tetragonal space group, 1-4, and classified as a porous molecular material owing to the presence of two types of distinct channels as a result of intermolecular hydrogen bonding. Compound 2 exhibits a differential gas adsorption property. The powder second-harmonic generating (SHG) measurements indicate that compound 2 shows a SHG efficiency 10 times greater than those of alpha-SiO2 and type-1 nonphase-matchable. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved. | - |
dc.format.extent | 5 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | 한국공업화학회 | - |
dc.title | Preparation and characterization of single crystals of tetrakis(4-(5,5-dimethyl-2-phenyl-1,3-dioxan-2-yl)phenyl)germane | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.jiec.2018.09.024 | - |
dc.identifier.bibliographicCitation | Journal of Industrial and Engineering Chemistry, v.69, pp 444 - 448 | - |
dc.identifier.kciid | ART002435763 | - |
dc.description.isOpenAccess | Y | - |
dc.identifier.wosid | 000452934600048 | - |
dc.identifier.scopusid | 2-s2.0-85054793295 | - |
dc.citation.endPage | 448 | - |
dc.citation.startPage | 444 | - |
dc.citation.title | Journal of Industrial and Engineering Chemistry | - |
dc.citation.volume | 69 | - |
dc.type.docType | Article | - |
dc.publisher.location | 대한민국 | - |
dc.subject.keywordAuthor | Organogermanium compound | - |
dc.subject.keywordAuthor | Single crystal | - |
dc.subject.keywordAuthor | Tetrahedral | - |
dc.subject.keywordAuthor | Gas adsorption | - |
dc.subject.keywordAuthor | Second-harmonic generating efficiency | - |
dc.subject.keywordPlus | POROUS MATERIAL | - |
dc.subject.keywordPlus | MORPHOLOGY | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.subject.keywordPlus | STABILITY | - |
dc.subject.keywordPlus | FRAMEWORK | - |
dc.subject.keywordPlus | PACKING | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
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