Beauvetetraones A-C, phomaligadione-derived polyketide dimers from the entomopathogenic fungus, Beauveria bassiana
DC Field | Value | Language |
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dc.contributor.author | Lee, Seoung Rak | - |
dc.contributor.author | Kuefner, Michelle | - |
dc.contributor.author | Park, Minji | - |
dc.contributor.author | Jung, Won Hee | - |
dc.contributor.author | Choi, Sang Un | - |
dc.contributor.author | Beemelmanns, Christine | - |
dc.contributor.author | Kim, Ki Hyun | - |
dc.date.available | 2019-05-28T01:40:10Z | - |
dc.date.issued | 2019-01 | - |
dc.identifier.issn | 2052-4129 | - |
dc.identifier.issn | 2052-4129 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/18315 | - |
dc.description.abstract | We report the isolation of two novel epimeric phomaligadione-derived polyketides, beauvetetraones A-B (1-2), from the entomopathogenic fungus Beauveria bassiana. Beauvetetraones A and B feature an unprecedented methylene-bridged phloroglucinol skeleton with a highly rearranged scaffold. In addition, a dimer of two phomaligadiones, named beauvetetraone C, was isolated for the first time from a natural source. The structures of compounds 1-3 including their absolute configurations were unambiguously assigned by NMR spectroscopic analyses, phenylglycine methyl ester (PGME) analysis, and quantum chemical ECD calculations. A putative biosynthetic pathway for beauvetetraones A-C is proposed. | - |
dc.format.extent | 5 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Beauvetetraones A-C, phomaligadione-derived polyketide dimers from the entomopathogenic fungus, Beauveria bassiana | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/c8qo01009a | - |
dc.identifier.bibliographicCitation | ORGANIC CHEMISTRY FRONTIERS, v.6, no.2, pp 162 - 166 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000457264600020 | - |
dc.identifier.scopusid | 2-s2.0-85060065734 | - |
dc.citation.endPage | 166 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 162 | - |
dc.citation.title | ORGANIC CHEMISTRY FRONTIERS | - |
dc.citation.volume | 6 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordPlus | GLYCOSIDES | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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