Effect of acidity of oxide support on the activity and stability of μ-nitrido diiron phthalocyanine complex
DC Field | Value | Language |
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dc.contributor.author | Cho, K. | - |
dc.contributor.author | Kim, H. | - |
dc.contributor.author | Nhựt, L.M. | - |
dc.contributor.author | Seo, K. | - |
dc.contributor.author | Kim, M.-G. | - |
dc.contributor.author | Kim, C. | - |
dc.date.available | 2019-05-28T03:34:22Z | - |
dc.date.issued | 2019-04 | - |
dc.identifier.issn | 0263-8762 | - |
dc.identifier.issn | 1744-3563 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/18533 | - |
dc.description.abstract | Various oxides, including Al 2 O 3 , Fe 2 O 3 , SiO 2 , and ZrO 2 , were employed as catalyst supports for the oxidation of cyclohexane by a μ-nitrido-bis[tetra(tert-butyl)phthalocyaninatoiron] complex. These oxide supports were characterized by Brunauer–Emmett–Teller surface area measurements and NH 3 temperature-programmed desorption analyses. The catalyst supported on Al 2 O 3 , which has the highest acidity among the oxides considered here, showed the best activity with a turnover number (TON) of ˜108.8, without any co-catalyst. Furthermore, recycle tests of the catalysts revealed a TON of 69.3 for the Al 2 O 3 -supported catalyst after the third run. The strongly acidic sites in the Al 2 O 3 support could be responsible for the strong adsorption of μ-nitrido diiron phthalocyanine, resulting in enhanced catalytic activity and stability. © 2019 Institution of Chemical Engineers | - |
dc.format.extent | 5 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | Institution of Chemical Engineers | - |
dc.title | Effect of acidity of oxide support on the activity and stability of μ-nitrido diiron phthalocyanine complex | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.cherd.2019.02.023 | - |
dc.identifier.bibliographicCitation | Chemical Engineering Research and Design, v.144, pp 429 - 433 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000465049200036 | - |
dc.identifier.scopusid | 2-s2.0-85062470756 | - |
dc.citation.endPage | 433 | - |
dc.citation.startPage | 429 | - |
dc.citation.title | Chemical Engineering Research and Design | - |
dc.citation.volume | 144 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordAuthor | Acidity | - |
dc.subject.keywordAuthor | Cyclohexane | - |
dc.subject.keywordAuthor | Oxidation | - |
dc.subject.keywordAuthor | Support | - |
dc.subject.keywordAuthor | μ-Nitrido diiron phthalocyanine | - |
dc.subject.keywordPlus | CYTOCHROME-P450 ENZYMES | - |
dc.subject.keywordPlus | SELECTIVE OXIDATION | - |
dc.subject.keywordPlus | MOLECULAR-OXYGEN | - |
dc.subject.keywordPlus | METAL-COMPLEXES | - |
dc.subject.keywordPlus | CYCLOHEXANE | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | METHANE | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | TEMPERATURE | - |
dc.subject.keywordPlus | WATER | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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