Organocatalytic Oxidative Cyclization of Amidoximes for the Synthesis of 1,2,4-Oxadiazolines
DC Field | Value | Language |
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dc.contributor.author | Soni, Vineet Kumar | - |
dc.contributor.author | Kim, Jun | - |
dc.contributor.author | Cho, Eun Jin | - |
dc.date.available | 2019-03-07T04:36:30Z | - |
dc.date.issued | 2018-07 | - |
dc.identifier.issn | 1615-4150 | - |
dc.identifier.issn | 1615-4169 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/1963 | - |
dc.description.abstract | Organocatalytic synthesis of bi- and tricyclic fused 1,2,4-oxadiazolines is reported. The reaction proceeds through oxidative cyclization of the corresponding amidoxime using 2,4,6-tris(4-fluorophenyl)pyrylium tetrafluoroborate (T(p-F)PPT) as the organocatalyst, and molecular oxygen as the green oxidant. During the transformation, T(p-F)PPT acts as both the electrophilic catalyst and photocatalyst, and the reaction is promoted by irradiation with visible light. The method introduced herein offers a straightforward route to the preparation of 1,2,4-oxadiazolines with different functionalities, and is highly atom economical. | - |
dc.format.extent | 6 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Organocatalytic Oxidative Cyclization of Amidoximes for the Synthesis of 1,2,4-Oxadiazolines | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/adsc.201800238 | - |
dc.identifier.bibliographicCitation | ADVANCED SYNTHESIS & CATALYSIS, v.360, no.14, pp 2626 - 2631 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000438710200005 | - |
dc.identifier.scopusid | 2-s2.0-85047458961 | - |
dc.citation.endPage | 2631 | - |
dc.citation.number | 14 | - |
dc.citation.startPage | 2626 | - |
dc.citation.title | ADVANCED SYNTHESIS & CATALYSIS | - |
dc.citation.volume | 360 | - |
dc.type.docType | Article | - |
dc.publisher.location | 독일 | - |
dc.subject.keywordAuthor | Organocatalysis | - |
dc.subject.keywordAuthor | Molecular oxygen | - |
dc.subject.keywordAuthor | Cyclization | - |
dc.subject.keywordAuthor | Nitrogen heterocycles | - |
dc.subject.keywordPlus | VISIBLE-LIGHT PHOTOREDOX | - |
dc.subject.keywordPlus | GAMMA-SECRETASE MODULATORS | - |
dc.subject.keywordPlus | 1,3-DIPOLAR CYCLOADDITION | - |
dc.subject.keywordPlus | TRIHETEROCYCLIC FRAMEWORK | - |
dc.subject.keywordPlus | NITRILE OXIDES | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | DISCOVERY | - |
dc.subject.keywordPlus | POTENT | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | 4,5-DIHYDRO-1,2,4-OXADIAZOLES | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Applied | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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