Rb3VO(O-2)(2)CO3: A Four-in-One Carbonatoperoxovanadate Exhibiting an Extremely Strong Second-Harmonic Generation Response
DC Field | Value | Language |
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dc.contributor.author | Zou, Guohong | - |
dc.contributor.author | Jo, Hongil | - |
dc.contributor.author | Lim, Seong-Ji | - |
dc.contributor.author | You, Tae-Soo | - |
dc.contributor.author | Ok, Kang Min | - |
dc.date.available | 2019-03-07T04:36:35Z | - |
dc.date.issued | 2018-07 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.issn | 1521-3773 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/1972 | - |
dc.description.abstract | A nonlinear optical (NLO) carbonatoperoxovanadate, Rb3VO(O-2)(2)CO3, was synthesized through a simple solution-evaporation method in phase-pure form. Single-crystal X-ray diffraction revealed that the structure of Rb3VO-(O-2)(2)CO3 consists of important noncentrosymmetric (NCS) chromophores, that is, pi-delocalized (CO3)(2-) groups, a second-order Jahn-Teller (SOJT) distortive V5+ cation, and pi-localized distorted O-2(2-) groups, as well as charge-balancing polarizable Rb+ ions. The powder second-harmonic generation (SHG) measurements indicated that Rb3VO(O-2)(2)CO3 is phase-matchable (TypeI) and exhibits a remarkably strong SHG response circa 21.0 times that of potassium dihydrogen phosphate (KDP), which is the largest efficiency observed among carbonate NLO materials. First-principles calculation analysis suggests that the extremely large SHG response of Rb3VO(O-2)(2)CO3 is attributed to the synergistic effect of the cooperation of all the constituting NCS chromophores. | - |
dc.format.extent | 4 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Rb3VO(O-2)(2)CO3: A Four-in-One Carbonatoperoxovanadate Exhibiting an Extremely Strong Second-Harmonic Generation Response | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/anie.201804354 | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.57, no.28, pp 8619 - 8622 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000437668700045 | - |
dc.identifier.scopusid | 2-s2.0-85049603792 | - |
dc.citation.endPage | 8622 | - |
dc.citation.number | 28 | - |
dc.citation.startPage | 8619 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 57 | - |
dc.type.docType | Article | - |
dc.publisher.location | 독일 | - |
dc.subject.keywordAuthor | carbonates | - |
dc.subject.keywordAuthor | nonlinear optics | - |
dc.subject.keywordAuthor | peroxovanadates | - |
dc.subject.keywordAuthor | rubidium | - |
dc.subject.keywordAuthor | second harmonic generation | - |
dc.subject.keywordPlus | NONLINEAR-OPTICAL MATERIAL | - |
dc.subject.keywordPlus | LARGE SHG ENHANCEMENT | - |
dc.subject.keywordPlus | ANIONIC GROUP-THEORY | - |
dc.subject.keywordPlus | NLO PROPERTIES | - |
dc.subject.keywordPlus | BORATE | - |
dc.subject.keywordPlus | RB | - |
dc.subject.keywordPlus | CRYSTAL | - |
dc.subject.keywordPlus | POLAR | - |
dc.subject.keywordPlus | CS | - |
dc.subject.keywordPlus | CSPBCO3F | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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