From a Metastable Layer to a Stable Ring: A Kinetic Study for Transformation Reactions of Li2Mo3TeO12 to Polyyoxometalates
DC Field | Value | Language |
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dc.contributor.author | Oh, Seung-Jin | - |
dc.contributor.author | Lim, Seong-Ji | - |
dc.contributor.author | You, Tae-Soo | - |
dc.contributor.author | Ok, Kang Min | - |
dc.date.available | 2019-03-07T04:40:43Z | - |
dc.date.issued | 2018-05 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.issn | 1521-3765 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/2177 | - |
dc.description.abstract | A metastable tellurite, Li2Mo3TeO12 revealing a corrugated layered structure in an extremely strained coordination environment was hydrothermally synthesized in high yield. Li2Mo3TeO12 undergoes Li+-exchange-driven facile structural transformation reactions to polyoxometalates. The kinetic data for the transformation reactions at various conditions were successfully obtained by simple lab-source powder X-ray diffraction. The investigation suggests that the solid-state transformation reactions may occur through a series of steps; substitution, decomposition, recombination, and precipitation. This new finding could be utilized in discovering functional metastable materials as well as understanding their phase transition mechanisms. | - |
dc.format.extent | 5 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | From a Metastable Layer to a Stable Ring: A Kinetic Study for Transformation Reactions of Li2Mo3TeO12 to Polyyoxometalates | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/chem.201704755 | - |
dc.identifier.bibliographicCitation | CHEMISTRY-A EUROPEAN JOURNAL, v.24, no.26, pp 6712 - 6716 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000431492500006 | - |
dc.identifier.scopusid | 2-s2.0-85046431781 | - |
dc.citation.endPage | 6716 | - |
dc.citation.number | 26 | - |
dc.citation.startPage | 6712 | - |
dc.citation.title | CHEMISTRY-A EUROPEAN JOURNAL | - |
dc.citation.volume | 24 | - |
dc.type.docType | Article | - |
dc.publisher.location | 독일 | - |
dc.subject.keywordAuthor | kinetics | - |
dc.subject.keywordAuthor | lithium | - |
dc.subject.keywordAuthor | metastable tellurites | - |
dc.subject.keywordAuthor | molybdenum | - |
dc.subject.keywordAuthor | X-ray diffraction | - |
dc.subject.keywordPlus | X-RAY-DIFFRACTION | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORKS | - |
dc.subject.keywordPlus | SOLVOTHERMAL CRYSTALLIZATION | - |
dc.subject.keywordPlus | DIMENSIONAL TELLURITES | - |
dc.subject.keywordPlus | HYDROTHERMAL SYNTHESIS | - |
dc.subject.keywordPlus | EXCHANGE | - |
dc.subject.keywordPlus | REVEALS | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | GROWTH | - |
dc.subject.keywordPlus | SERIES | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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