Lone Pairs as Chemical Scissors in New Antimony Oxychlorides, Sb2ZnO3Cl2 and Sb16Cd8O25Cl14
DC Field | Value | Language |
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dc.contributor.author | Jo, Vinna | - |
dc.contributor.author | Kim, Min Kyung | - |
dc.contributor.author | Lee, Dong Woo | - |
dc.contributor.author | Shim, Il-Wun | - |
dc.contributor.author | Ok, Kang Min | - |
dc.date.available | 2019-05-30T01:40:06Z | - |
dc.date.issued | 2010-03 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.issn | 1520-510X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/22564 | - |
dc.description.abstract | Two new metal antimony oxychlorides, Sb2ZnO3Cl2 and Sb16Cd8O25Cl14, have been synthesized by solid-state reactions using Sb2O3 and ZnCl2 (or CdCl2) as reagents. The structures of Sb2ZnO3Cl2 and Sb16Cd8O25Cl14 have been determined by single-crystal X-ray diffraction. Both of the reported materials contain Sb3+ cations that are in an asymmetric coordination environment attributable to their stereoactive lone pair. Sb2ZnO3Cl2 has a novel two-dimensional layered structure consisting of distorted ZnO2Cl2 tetrahedra and SbO3 polyhedra. Sb16Cd8O25Cl14 exhibits a one-dimensional structure consisting of Sb3+-Cd2+-oxide rods, Cd2+-chloride double chains, and isolated Cl- ions. Complete separation of the halophile and chalcophile moieties is observed from the reported materials. Detailed structural analysis, IR spectra, thermogravimetric analysis, ion-exchange reactions, and dipole moment calculations are presented. Crystal data: Sb2ZnO3Cl2, orthorhombic, space group Pnma (No. 62), a = 17.124(4) angstrom, b = 5.5598(12) angstrom, c = 6.4823(14) angstrom, V = 617.2(2) angstrom(3), and Z = 4; Sb16Cd8O25Cl14, monoclinic, space group I2/m (No. 12), a = 14.251(3) angstrom, b = 3.9895(8) angstrom, C = 21.145(4) angstrom, beta = 97.35(3)degrees, V = 1192.3(4) angstrom(3), and Z = 8. | - |
dc.format.extent | 6 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Lone Pairs as Chemical Scissors in New Antimony Oxychlorides, Sb2ZnO3Cl2 and Sb16Cd8O25Cl14 | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/ic902493r | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.49, no.6, pp 2990 - 2995 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000275164900052 | - |
dc.identifier.scopusid | 2-s2.0-77949400180 | - |
dc.citation.endPage | 2995 | - |
dc.citation.number | 6 | - |
dc.citation.startPage | 2990 | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 49 | - |
dc.type.docType | Article | - |
dc.publisher.location | 미국 | - |
dc.subject.keywordPlus | BOND-VALENCE PARAMETERS | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | MAGNETIC-PROPERTIES | - |
dc.subject.keywordPlus | CHLORIDE COMPLEXES | - |
dc.subject.keywordPlus | CENTER DISTORTION | - |
dc.subject.keywordPlus | ALPHA-PBO | - |
dc.subject.keywordPlus | X-RAY | - |
dc.subject.keywordPlus | BR | - |
dc.subject.keywordPlus | STEREOCHEMISTRY | - |
dc.subject.keywordPlus | CL | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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