New Noncentrosymmetric Material - [N(CH3)(4)]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra
DC Field | Value | Language |
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dc.contributor.author | Choi, Myung-Ho | - |
dc.contributor.author | Kim, Sang-Hwan | - |
dc.contributor.author | Chang, Hong-Young | - |
dc.contributor.author | Halasyamani, P. Shiv | - |
dc.contributor.author | Ok, Kang Min | - |
dc.date.available | 2019-05-30T02:42:52Z | - |
dc.date.issued | 2009-09 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.issn | 1520-510X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/23016 | - |
dc.description.abstract | A new organically templated noncentrosymmetric polar zinc chloride, [N(CH3)(4)]ZnCl3, has been synthesized hydrothermally, and the structure was determined by single crystal X-ray diffraction. The reported material exhibits a unidimensional crystal structure consisting of chains of anionic ZnCl4 tetrahedra that are separated by [N(CH3)(4)](+) cations. Second-harmonic generation (SHG) measurement on the noncentrosymmetric [N(CH3)(4)]ZnCl3, using 1064 nm radiation, indicate the material has a SHG efficiency of approximately 15 x alpha-SiO2. Additional SHG measurements indicate the material is nonphase-matchable (type 1). In addition, converse piezoelectric measurements revealed d(33) values of 10 pm/V. Thermogravimetric analysis, UV-vis diffuse reflectance, and infrared spectroscopy were also performed, as were electronic structure calculations.. Crystal data: [N(CH3)(4)]ZnCl3, orthorhombic, space group Pmc2(1) (No. 26), with a = 7.2350(14) angstrom, b = 8.8210(18) angstrom, c = 15.303(3) angstrom, V = 976.6(3) angstrom(3), and Z = 4. | - |
dc.format.extent | 7 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | New Noncentrosymmetric Material - [N(CH3)(4)]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/ic901064q | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.48, no.17, pp 8376 - 8382 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000269313500045 | - |
dc.identifier.scopusid | 2-s2.0-69549111664 | - |
dc.citation.endPage | 8382 | - |
dc.citation.number | 17 | - |
dc.citation.startPage | 8376 | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 48 | - |
dc.type.docType | Article | - |
dc.publisher.location | 미국 | - |
dc.subject.keywordPlus | 2ND-HARMONIC GENERATING PROPERTIES | - |
dc.subject.keywordPlus | BOND-VALENCE PARAMETERS | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | AMMONIUM TETRACHLOROZINCATE | - |
dc.subject.keywordPlus | CENTER DISTORTION | - |
dc.subject.keywordPlus | ZINC-CHLORIDE | - |
dc.subject.keywordPlus | OXIDES | - |
dc.subject.keywordPlus | ANION | - |
dc.subject.keywordPlus | STEREOCHEMISTRY | - |
dc.subject.keywordPlus | SOLIDS | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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