Potentiometric Response of a Neutral-carrier-based Membrane to Aqueous Mercury in Cl--rich Media

Abstract

The unique potentiometric response of mercury sensors was investigated in aqueous Cl--rich media, which are often encountered in natural, especially biological samples. The conventional neutral-carrier-based Hg(II)-ISEs are not practically useful because the Cl- concentrations in natural aqueous samples are normally too high for mercury to be present in the form of Hg2+. Negative potentiometric slopes, which are the opposite behavior of the previously reported Hg(II)-ISEs, were experimentally confirmed and quantitatively reasoned based on the aqueous solution equilibrium of Hg2+.