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Mechanism of action of base-catalyzed oxygenation of phenol derivatives
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Lee, Duck-Hyung | - |
| dc.contributor.author | Son, Jung Beom | - |
| dc.contributor.author | Jung, Seokwon | - |
| dc.contributor.author | Song, Jihey | - |
| dc.contributor.author | Ham, Seung Wook | - |
| dc.date.available | 2019-05-30T07:35:31Z | - |
| dc.date.issued | 2005-11 | - |
| dc.identifier.issn | 0040-4039 | - |
| dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/24480 | - |
| dc.description.abstract | Cyclopropyl derivative of 2,6-di-tert-butylphenol is synthesized as a probe to investigate the mechanism of base-catalyzed autooxidation of phenol derivatives. Our study indicates that one electron reduction of molecular oxygen from phenolate gives phenoxyl radical 3, a key intermediate of autooxidation. The coupling of phenoxyl radical and superoxide radical gives peroxylate anion 4 and produces the final epoxy alcohol adduct 6. (c) 2005 Published by Elsevier Ltd. | - |
| dc.format.extent | 3 | - |
| dc.language | 영어 | - |
| dc.language.iso | ENG | - |
| dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
| dc.title | Mechanism of action of base-catalyzed oxygenation of phenol derivatives | - |
| dc.type | Article | - |
| dc.identifier.doi | 10.1016/j.tetlet.2005.09.029 | - |
| dc.identifier.bibliographicCitation | TETRAHEDRON LETTERS, v.46, no.45, pp 7721 - 7723 | - |
| dc.description.isOpenAccess | N | - |
| dc.identifier.wosid | 000232738500012 | - |
| dc.identifier.scopusid | 2-s2.0-26444602000 | - |
| dc.citation.endPage | 7723 | - |
| dc.citation.number | 45 | - |
| dc.citation.startPage | 7721 | - |
| dc.citation.title | TETRAHEDRON LETTERS | - |
| dc.citation.volume | 46 | - |
| dc.type.docType | Article | - |
| dc.publisher.location | 영국 | - |
| dc.subject.keywordAuthor | autooxidation | - |
| dc.subject.keywordAuthor | phenolate | - |
| dc.subject.keywordAuthor | mechanism | - |
| dc.subject.keywordAuthor | radical | - |
| dc.subject.keywordPlus | PICOSECOND RADICAL KINETICS | - |
| dc.subject.keywordPlus | POTASSIUM SUPEROXIDE | - |
| dc.subject.keywordPlus | VITAMIN-K | - |
| dc.subject.keywordPlus | MODEL | - |
| dc.subject.keywordPlus | OXIDATION | - |
| dc.subject.keywordPlus | ION | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
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