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Facile Synthesis of BiVO 4 for Visible-Light-Induced C−C Bond Cleavage of Alkenes to Generate Carbonyls
- Issue Date
- Jul-2019
- Publisher
- Wiley-VCH Verlag
- Keywords
- alkene; bismuth vanadate; C−C bond cleavage; molecular oxygen; photocatalysis
- Citation
- ChemSusChem, v.12, no.13, pp 3018 - 3022
- Pages
- 5
- Journal Title
- ChemSusChem
- Volume
- 12
- Number
- 13
- Start Page
- 3018
- End Page
- 3022
- ISSN
- 1864-5631
1864-564X
- Abstract
- BiVO 4 crystals synthesized by an ultrasonic-assisted method (Sono-BiVO 4 ) showed improved efficiency as a heterogeneous photocatalyst under visible-light irradiation. Sono-BiVO 4 was successfully used for the C−C bond cleavage of alkenes to generate carbonyl compounds. Styrene derivatives were converted into carbonyl compounds in the presence of Sono-BiVO 4 under highly sustainable conditions requiring only natural sources, that is, molecular oxygen, visible light, and water at room temperature. Additionally, Sono-BiVO 4 could be easily separated from the reaction mixture and reused. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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