Reaction-based fluorometric analysis of: N -bromosuccinimide by oxidative deprotection of dithiane
DC Field | Value | Language |
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dc.contributor.author | Lee, Yu Jeong | - |
dc.contributor.author | Choi, Myung Gil | - |
dc.contributor.author | Park, Tae Jung | - |
dc.contributor.author | Chang, Suk-Kyu | - |
dc.date.available | 2019-06-26T01:31:45Z | - |
dc.date.issued | 2019-05 | - |
dc.identifier.issn | 0003-2654 | - |
dc.identifier.issn | 1364-5528 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/26368 | - |
dc.description.abstract | In this study, a fluorescent probe is developed for the first time for N-bromosuccinimide (NBS), a synthetically and analytically important compound. Pyrene-dithiane-based probe 1 showed prominently selective and sensitive signaling behavior toward NBS owing to the oxidative cleavage of the dithiane protecting group of 1-pyrenecarboxaldehyde. The NBS-selective signaling of the probe was possible under competitive conditions in the presence of common metal ions and anions as a background. The detection limit of the probe for NBS was found to be 5.6 × 10 -8 M (10.0 ppb). The signaling product was sufficiently stable under the oxidative stress of NBS in contrast to another tested compound, 6-methoxy-2-naphthaldehyde-based dithiane derivative 2, which showed a gradually decaying response because of the reaction of the signaling product with the residual NBS. In the practical application of the probe, a smartphone was used as a stand-alone device, and the fluorometric assays of the commercial NBS reagents could be conducted rapidly and in a convenient manner. © 2019 The Royal Society of Chemistry. | - |
dc.format.extent | 7 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | Royal Society of Chemistry | - |
dc.title | Reaction-based fluorometric analysis of: N -bromosuccinimide by oxidative deprotection of dithiane | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/c8an02125b | - |
dc.identifier.bibliographicCitation | Analyst, v.144, no.10, pp 3267 - 3273 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000474058800005 | - |
dc.identifier.scopusid | 2-s2.0-85065651392 | - |
dc.citation.endPage | 3273 | - |
dc.citation.number | 10 | - |
dc.citation.startPage | 3267 | - |
dc.citation.title | Analyst | - |
dc.citation.volume | 144 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordPlus | INJECTION CHEMILUMINESCENCE DETERMINATION | - |
dc.subject.keywordPlus | SPECTROPHOTOMETRIC METHODS | - |
dc.subject.keywordPlus | CARBONYL-COMPOUNDS | - |
dc.subject.keywordPlus | HIGHLY EFFICIENT | - |
dc.subject.keywordPlus | 1,3-DITHIANES | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | 1,3-DITHIOLANES | - |
dc.subject.keywordPlus | CHEMODOSIMETER | - |
dc.subject.keywordPlus | HG2+ | - |
dc.subject.keywordPlus | ACID | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Analytical | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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