New quaternary alkali metal cadmium selenites, A(2)Cd(SeO3)(2) (A = K, Rb, and Cs) and Li2Cd3(SeO3)(4)
DC Field | Value | Language |
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dc.contributor.author | Lu, Minfeng | - |
dc.contributor.author | Jo, Hongil | - |
dc.contributor.author | Oh, Seung-Jin | - |
dc.contributor.author | Ok, Kang Min | - |
dc.date.available | 2019-03-08T07:36:13Z | - |
dc.date.issued | 2017-12 | - |
dc.identifier.issn | 0022-4596 | - |
dc.identifier.issn | 1095-726X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/3522 | - |
dc.description.abstract | A series of new alkali metal cadmium selenites, A(2)Cd(SeO3)(2) (A = K, Rb, and Cs) and Li2Cd3(SeO3)(4) have been synthesized in phase pure forms through hydrothermal and solid-state reactions. Structural analyses using single crystal X-ray diffraction indicate that while A(2)Cd(SeO3)(2) and Li2Cd3(SeO3)(4) reveal layered structures consisting of CdO6 and SeO3 polyhedra, their symmetry, bonding modes, and the orientation of lone pairs on Se4+ cations are different. A closer examination suggests that the observed structural variations found in the reported materials are attributed to the structure-directing effect of alkali metal cations with different sizes. Scanning electron microscopy/energy dispersive analysis by X-ray, thermogravimetric analysis, Infrared and UV-vis diffuse reflectance spectroscopy, transformation reactions under hydrothermal conditions, and local dipole moment calculations for the reported materials are also reported. | - |
dc.format.extent | 6 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | ACADEMIC PRESS INC ELSEVIER SCIENCE | - |
dc.title | New quaternary alkali metal cadmium selenites, A(2)Cd(SeO3)(2) (A = K, Rb, and Cs) and Li2Cd3(SeO3)(4) | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.jssc.2017.09.014 | - |
dc.identifier.bibliographicCitation | JOURNAL OF SOLID STATE CHEMISTRY, v.256, pp 213 - 218 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000413134600030 | - |
dc.identifier.scopusid | 2-s2.0-85029507426 | - |
dc.citation.endPage | 218 | - |
dc.citation.startPage | 213 | - |
dc.citation.title | JOURNAL OF SOLID STATE CHEMISTRY | - |
dc.citation.volume | 256 | - |
dc.type.docType | Article | - |
dc.publisher.location | 미국 | - |
dc.subject.keywordAuthor | Alakali metal selenites | - |
dc.subject.keywordAuthor | Synthesis | - |
dc.subject.keywordAuthor | Structures | - |
dc.subject.keywordAuthor | Lone pairs | - |
dc.subject.keywordAuthor | Single crystal X-ray diffraction | - |
dc.subject.keywordPlus | SOLID-STATE SYNTHESIS | - |
dc.subject.keywordPlus | SOJT DISTORTIVE CATIONS | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | FRAMEWORK STRUCTURES | - |
dc.subject.keywordPlus | MAGNETIC-PROPERTIES | - |
dc.subject.keywordPlus | OXIDES | - |
dc.subject.keywordPlus | SERIES | - |
dc.subject.keywordPlus | BUETSCHLIITE | - |
dc.subject.keywordPlus | SIZE | - |
dc.subject.keywordPlus | NA | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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