Impact of highly crystalline, isoindigo-based small-molecular additives for enhancing the performance of all-polymer solar cells
DC Field | Value | Language |
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dc.contributor.author | Cho, Han-Hee | - |
dc.contributor.author | Han, Gibok | - |
dc.contributor.author | Younts, Robert | - |
dc.contributor.author | Lee, Wonho | - |
dc.contributor.author | Gautam, Bhoj R. | - |
dc.contributor.author | Lee, Seungjin | - |
dc.contributor.author | Lee, Changyeon | - |
dc.contributor.author | Kim, Taesu | - |
dc.contributor.author | Kim, Felix Sunjoo | - |
dc.contributor.author | Gundogdu, Kenan | - |
dc.contributor.author | Kim, Bumjoon J. | - |
dc.date.available | 2019-03-08T07:38:25Z | - |
dc.date.issued | 2017-10 | - |
dc.identifier.issn | 2050-7488 | - |
dc.identifier.issn | 2050-7496 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/3757 | - |
dc.description.abstract | We have developed a simple yet versatile approach for enhancing the performance of all-polymer solar cells (all-PSCs) using a highly crystalline small-molecular additive, 6,6 '-dithiopheneisoindigo (DTI). The DTI additive in a blend of PTB7-Th donor and P(NDI2HD-T) acceptor enhances the power conversion efficiency of all-PSCs from 5.9 to 6.8%. Based on the analyses of the electrical, optical, and structural properties of all-PSCs, it is suggested that DTI additives promote tighter pi-pi packing and larger sizes of crystalline domains. Such morphological changes of the PTB7-Th: P(NDI2HD-T) blend films upon the addition of DTI enhance the exciton lifetime and diffusion length, which are proved by static and femtosecond-transient absorption spectroscopies and time-resolved photoluminescence. As a result of improved exciton dissociation probability and charge transport, the short-circuit current density of all-PSCs is greatly increased. Importantly, we also show that the DTI additive can be applied to other all-PSC systems with different polymer donors and naphthalene diimide (NDI)-based polymer acceptors, where the efficiencies of all-PSCs are enhanced by 10-20%. | - |
dc.format.extent | 9 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Impact of highly crystalline, isoindigo-based small-molecular additives for enhancing the performance of all-polymer solar cells | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/c7ta06939a | - |
dc.identifier.bibliographicCitation | JOURNAL OF MATERIALS CHEMISTRY A, v.5, no.40, pp 21291 - 21299 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000413189100024 | - |
dc.identifier.scopusid | 2-s2.0-85031675110 | - |
dc.citation.endPage | 21299 | - |
dc.citation.number | 40 | - |
dc.citation.startPage | 21291 | - |
dc.citation.title | JOURNAL OF MATERIALS CHEMISTRY A | - |
dc.citation.volume | 5 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordPlus | POWER CONVERSION EFFICIENCY | - |
dc.subject.keywordPlus | FULLERENE-POLYMER | - |
dc.subject.keywordPlus | ELECTRON-MOBILITY | - |
dc.subject.keywordPlus | BLEND MORPHOLOGY | - |
dc.subject.keywordPlus | ACCEPTOR | - |
dc.subject.keywordPlus | ORIENTATION | - |
dc.subject.keywordPlus | AGGREGATION | - |
dc.subject.keywordPlus | SOLVENT | - |
dc.subject.keywordPlus | PACKING | - |
dc.subject.keywordPlus | WEIGHT | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Energy & Fuels | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Energy & Fuels | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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