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Organophotocatalytic Arene Functionalization: C-C and C-B Bond Formation
- Issue Date
- Dec-2019
- Publisher
- American Chemical Society
- Citation
- Organic Letters, v.21, no.24, pp 9950 - 9953
- Pages
- 4
- Journal Title
- Organic Letters
- Volume
- 21
- Number
- 24
- Start Page
- 9950
- End Page
- 9953
- ISSN
- 1523-7060
1523-7052
- Abstract
- Organophotocatalytic C-C and C-B bond formation reactions of aryl halides have been developed in the presence of an organophotosensitizer, 3,7-di([1,1′-biphenyl]-4-yl)-10-(4-(trifluoromethyl)phenyl)-10H-phenoxazine that has highly negative reduction potential at its photoexcited state. The developed reaction conditions are mild and allow the intermolecular C-C bond formation of the generated aryl radical with electron-rich (hetero)arenes and C-B bond formation with bis(pinacolato)diboron. © 2019 American Chemical Society.
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