Recent Innovation of Metal-Organic Frameworks for Carbon Dioxide Photocatalytic Reduction
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kidanemariam, Alemayehu | - |
dc.contributor.author | Lee, Jiwon | - |
dc.contributor.author | Park, Juhyun | - |
dc.date.available | 2020-03-07T01:40:26Z | - |
dc.date.issued | 2019-12 | - |
dc.identifier.issn | 2073-4360 | - |
dc.identifier.issn | 2073-4360 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/37627 | - |
dc.description.abstract | The accumulation of carbon dioxide (CO2) pollutants in the atmosphere begets global warming, forcing us to face tangible catastrophes worldwide. Environmental affability, affordability, and efficient CO2 metamorphotic capacity are critical factors for photocatalysts; metal-organic frameworks (MOFs) are one of the best candidates. MOFs, as hybrid organic ligand and inorganic nodal metal with tailorable morphological texture and adaptable electronic structure, are contemporary artificial photocatalysts. The semiconducting nature and porous topology of MOFs, respectively, assists with photogenerated multi-exciton injection and adsorption of substrate proximate to void cavities, thereby converting CO2. The vitality of the employment of MOFs in CO2 photolytic reaction has emerged from the fact that they are not only an inherently eco-friendly weapon for pollutant extermination, but also a potential tool for alleviating foreseeable fuel crises. The excellent synergistic interaction between the central metal and organic linker allows decisive implementation for the design, integration, and application of the catalytic bundle. In this review, we presented recent MOF headway focusing on reports of the last three years, exhaustively categorized based on central metal-type, and novel discussion, from material preparation to photocatalytic, simulated performance recordings of respective as-synthesized materials. The selective CO2 reduction capacities into syngas or formate of standalone or composite MOFs with definite photocatalytic reaction conditions was considered and compared. | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | MDPI | - |
dc.title | Recent Innovation of Metal-Organic Frameworks for Carbon Dioxide Photocatalytic Reduction | - |
dc.type | Article | - |
dc.identifier.doi | 10.3390/polym11122090 | - |
dc.identifier.bibliographicCitation | POLYMERS, v.11, no.12 | - |
dc.description.isOpenAccess | Y | - |
dc.identifier.wosid | 000507624500183 | - |
dc.identifier.scopusid | 2-s2.0-85079098927 | - |
dc.citation.number | 12 | - |
dc.citation.title | POLYMERS | - |
dc.citation.volume | 11 | - |
dc.type.docType | Review | - |
dc.publisher.location | 스위스 | - |
dc.subject.keywordAuthor | metal-organic frameworks | - |
dc.subject.keywordAuthor | composite MOFs | - |
dc.subject.keywordAuthor | photosensitizer integrated MOFs | - |
dc.subject.keywordAuthor | heterostructure quantum dot-MOFs assembly | - |
dc.subject.keywordAuthor | metal ion doping | - |
dc.subject.keywordAuthor | heterogeneous photocatalyst | - |
dc.subject.keywordAuthor | CO2 transformation | - |
dc.subject.keywordAuthor | CO2 reduction | - |
dc.subject.keywordPlus | DRIVEN CO2 REDUCTION | - |
dc.subject.keywordPlus | HYBRID MEMBRANE REACTORS | - |
dc.subject.keywordPlus | ATOMIC LAYER DEPOSITION | - |
dc.subject.keywordPlus | DOT SOLAR-CELLS | - |
dc.subject.keywordPlus | ELECTRICAL-CONDUCTIVITY | - |
dc.subject.keywordPlus | CHARGE SEPARATION | - |
dc.subject.keywordPlus | HYDROGEN STORAGE | - |
dc.subject.keywordPlus | ELECTROCHEMICAL REDUCTION | - |
dc.subject.keywordPlus | PHOTOCHEMICAL REDUCTION | - |
dc.subject.keywordPlus | IMIDAZOLATE FRAMEWORKS | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
84, Heukseok-ro, Dongjak-gu, Seoul, Republic of Korea (06974)02-820-6194
COPYRIGHT 2019 Chung-Ang University All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.