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Copper(i)/DM-SEGPHOS-catalyzed enantio- and diastereoselective conjugate boration to alpha-alkylidene-gamma-lactams
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | George, Jimit | - |
| dc.contributor.author | Kim, Hun Young | - |
| dc.contributor.author | Oh, Kyungsoo | - |
| dc.date.available | 2020-04-10T02:20:57Z | - |
| dc.date.issued | 2020-02-21 | - |
| dc.identifier.issn | 2052-4129 | - |
| dc.identifier.issn | 2052-4129 | - |
| dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/38169 | - |
| dc.description.abstract | A combination of CuCl and DM-SEGPHOS catalyst system has allowed the development of highly enantioselective and diastereoselective conjugate addition of bis(pinacolato)diboron to alpha-alkylidene-gamma-lactams. The key structural feature of conjugate acceptors, alpha-alkylidene-gamma-lactams, was identified as the carbamate group such as N-Boc and N-Cbz, where the typical low reactivity and stereoselectivity issues associated with alpha,beta-unsaturated lactams as conjugate acceptors were resolved. | - |
| dc.format.extent | 6 | - |
| dc.language | 영어 | - |
| dc.language.iso | ENG | - |
| dc.publisher | ROYAL SOC CHEMISTRY | - |
| dc.title | Copper(i)/DM-SEGPHOS-catalyzed enantio- and diastereoselective conjugate boration to alpha-alkylidene-gamma-lactams | - |
| dc.type | Article | - |
| dc.identifier.doi | 10.1039/c9qo01504c | - |
| dc.identifier.bibliographicCitation | ORGANIC CHEMISTRY FRONTIERS, v.7, no.4, pp 709 - 714 | - |
| dc.description.isOpenAccess | N | - |
| dc.identifier.wosid | 000515578100009 | - |
| dc.identifier.scopusid | 2-s2.0-85079828934 | - |
| dc.citation.endPage | 714 | - |
| dc.citation.number | 4 | - |
| dc.citation.startPage | 709 | - |
| dc.citation.title | ORGANIC CHEMISTRY FRONTIERS | - |
| dc.citation.volume | 7 | - |
| dc.type.docType | Article | - |
| dc.publisher.location | 영국 | - |
| dc.subject.keywordPlus | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | - |
| dc.subject.keywordPlus | ENANTIOSELECTIVE BETA-BORATION | - |
| dc.subject.keywordPlus | CATALYTIC ASYMMETRIC-SYNTHESIS | - |
| dc.subject.keywordPlus | ESTERS | - |
| dc.subject.keywordPlus | ADDITIONS | - |
| dc.subject.keywordPlus | HYDROGENATION | - |
| dc.subject.keywordPlus | HYDROBORATION | - |
| dc.subject.keywordPlus | BORYLATION | - |
| dc.subject.keywordPlus | TERTIARY | - |
| dc.subject.keywordPlus | BOND | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
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