Chemoselective hydrogenation of α,β-unsaturated carbonyl compounds using a recyclable Ru catalyst embedded on a bisphosphine based POP
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Padmanaban, Sudakar | - |
dc.contributor.author | Lee, Yunho | - |
dc.contributor.author | Yoon, Sungho | - |
dc.date.accessioned | 2021-06-18T07:14:18Z | - |
dc.date.available | 2021-06-18T07:14:18Z | - |
dc.date.issued | 2021-02-25 | - |
dc.identifier.issn | 1226-086X | - |
dc.identifier.issn | 1876-794X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/44124 | - |
dc.description.abstract | Selective hydrogenation of the carbonyl functional group of α,β-unsaturated carbonyl compounds affords industrially important allylic alcohols. However, achieving the selective reduction of the carbonyl group in the presence of the activated olefinic group is challenging. Therefore, the development of a highly chemoselective, efficient, and recyclable catalyst for this transformation is greatly desirable from the industrial and environmental viewpoints. In this study, a Ru-immobilized bisphosphine-based porous organic polymer (Ru@PP-POP) was used as an efficient heterogeneous catalyst for chemoselective hydrogenation of cinnamaldehyde (CAL) to cinnamyl alcohol with high chemoselectivity (98%) and excellent recyclability. To the best of our knowledge, the catalyst, Ru@PP-POP showed a high turnover number (970) and a high turnover frequency (240 h−1) which is the best activity obtained using a phosphine based heterogeneous Ru-catalyst in this transformation. © 2020 The Korean Society of Industrial and Engineering Chemistry | - |
dc.format.extent | 7 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | Korean Society of Industrial Engineering Chemistry | - |
dc.title | Chemoselective hydrogenation of α,β-unsaturated carbonyl compounds using a recyclable Ru catalyst embedded on a bisphosphine based POP | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.jiec.2020.11.007 | - |
dc.identifier.bibliographicCitation | Journal of Industrial and Engineering Chemistry, v.94, pp 361 - 367 | - |
dc.identifier.kciid | ART002686589 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000609243700011 | - |
dc.identifier.scopusid | 2-s2.0-85097462500 | - |
dc.citation.endPage | 367 | - |
dc.citation.startPage | 361 | - |
dc.citation.title | Journal of Industrial and Engineering Chemistry | - |
dc.citation.volume | 94 | - |
dc.type.docType | Article | - |
dc.publisher.location | 미국 | - |
dc.subject.keywordAuthor | Allylic alcohol | - |
dc.subject.keywordAuthor | Chemoselective hydrogenation | - |
dc.subject.keywordAuthor | Green Chemistry | - |
dc.subject.keywordAuthor | Heterogeneous catalysis | - |
dc.subject.keywordAuthor | Ru catalysis | - |
dc.subject.keywordAuthor | α,β-Unsaturated carbonyl compounds | - |
dc.subject.keywordPlus | Catalyst supports | - |
dc.subject.keywordPlus | Hydrogenation | - |
dc.subject.keywordPlus | Organic polymers | - |
dc.subject.keywordPlus | Phosphorus compounds | - |
dc.subject.keywordPlus | Ruthenium | - |
dc.subject.keywordPlus | Selective catalytic reduction | - |
dc.subject.keywordPlus | Unsaturated compounds | - |
dc.subject.keywordPlus | Chemoselective hydrogenation | - |
dc.subject.keywordPlus | Heterogeneous catalyst | - |
dc.subject.keywordPlus | Porous organic polymers | - |
dc.subject.keywordPlus | Recyclable catalyst | - |
dc.subject.keywordPlus | Selective hydrogenation | - |
dc.subject.keywordPlus | Selective reduction | - |
dc.subject.keywordPlus | Turnover frequency | - |
dc.subject.keywordPlus | Unsaturated carbonyl compounds | - |
dc.subject.keywordPlus | Carbonyl compounds | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
84, Heukseok-ro, Dongjak-gu, Seoul, Republic of Korea (06974)02-820-6194
COPYRIGHT 2019 Chung-Ang University All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.