Eco-friendly upconversion of limestone into value-added calcium formate
DC Field | Value | Language |
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dc.contributor.author | Gunasekar, Gunniya Hariyanandam | - |
dc.contributor.author | Park, Hongjin | - |
dc.contributor.author | Padmanaban, Sudakar | - |
dc.contributor.author | Yoon, Sungho | - |
dc.date.accessioned | 2021-06-18T07:14:42Z | - |
dc.date.available | 2021-06-18T07:14:42Z | - |
dc.date.issued | 2020-08-07 | - |
dc.identifier.issn | 1463-9262 | - |
dc.identifier.issn | 1463-9270 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/44153 | - |
dc.description.abstract | Although CaCO(3)is a naturally available, inexpensive, abundant and extensively used chemical in various industries, to date, most of its conversions liberate CO(2)into the atmosphere, which accounts for about 5-6% of global anthropogenic CO(2)emission. Herein, the first synthesis of calcium formate (CF) by hydrogenation of an aqueous mixture of CaCO(3)and CO(2)using a heterogeneous catalyst in an unconventional CO(2)reducing manner is reported. The phosphine-based heterogenized Ru catalyst efficiently converts CaCO(3)into CF with good selectivity (>99%) and is readily separated from the reaction product, resulting in promising recycling ability. Thus, this work provides a promising strategy for the design of green and sustainable conversion of carbonate minerals in industry. | - |
dc.format.extent | 7 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Eco-friendly upconversion of limestone into value-added calcium formate | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/d0gc01089h | - |
dc.identifier.bibliographicCitation | GREEN CHEMISTRY, v.22, no.15, pp 4995 - 5001 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000555342200015 | - |
dc.identifier.scopusid | 2-s2.0-85089672969 | - |
dc.citation.endPage | 5001 | - |
dc.citation.number | 15 | - |
dc.citation.startPage | 4995 | - |
dc.citation.title | GREEN CHEMISTRY | - |
dc.citation.volume | 22 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | CATALYTIC-HYDROGENATION | - |
dc.subject.keywordPlus | CO2 HYDROGENATION | - |
dc.subject.keywordPlus | IRIDIUM COMPLEX | - |
dc.subject.keywordPlus | METHANOL | - |
dc.subject.keywordPlus | LIGAND | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Green & Sustainable Science & Technology | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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