Syntheses, Structures, and Characterization of Quaternary Tellurites, Li3MTe4O11 (M = Al, Ga, and Fe)
DC Field | Value | Language |
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dc.contributor.author | Lu, Minfeng | - |
dc.contributor.author | Jo, Hongil | - |
dc.contributor.author | Oh, Seung-Jin | - |
dc.contributor.author | Lee, Suheon | - |
dc.contributor.author | Choi, Kwang-Yong | - |
dc.contributor.author | Yu, Yang | - |
dc.contributor.author | Ok, Kang Min | - |
dc.date.available | 2019-03-08T08:56:13Z | - |
dc.date.issued | 2017-05 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.issn | 1520-510X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/4445 | - |
dc.description.abstract | Three new quaternary lithium metal tellurites, Li3MTe4O11 (M = Al, Ga, and Fe), have been synthesized through hydrothermal and solid-state reactions by heating a mixture of LiOH center dot H2O, TeO2, and M2O3. The structures of the title compounds have been determined by single-crystal and powder X-ray diffraction. Li3MTe4O11 reveal three-dimensional (3D) frameworks that consist of MO6 octahedra, TeO3 trigonal pyramids, and TeO4 polyhedra. The variable coordination mode of Te4+ within the framework leads to the formation of 1D channels that host Li+ cations on both tetrahedral and octahedral sites. The bulk and grain boundary Li+ ion conductivities for a Li3FeTe4O11 pellet in open air are estimated to be 1.0 x 10(-4) and 2.7 x 10(-6) S cm(-1), respectively, at room temperature from the impedance profile analysis. A lower activation energy of 19.9 kJ mol(-1) is obtained for the system, which is similar to that of Li10GeP2S12 (24 kJ mol(-1)). Detailed characterizations such as thermal, spectroscopic, and magnetic properties for the reported materials are also reported. | - |
dc.format.extent | 7 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Syntheses, Structures, and Characterization of Quaternary Tellurites, Li3MTe4O11 (M = Al, Ga, and Fe) | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/acs.inorgchem.7b00530 | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.56, no.10, pp 5873 - 5879 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000401593800043 | - |
dc.identifier.scopusid | 2-s2.0-85019445249 | - |
dc.citation.endPage | 5879 | - |
dc.citation.number | 10 | - |
dc.citation.startPage | 5873 | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 56 | - |
dc.type.docType | Article | - |
dc.publisher.location | 미국 | - |
dc.subject.keywordPlus | LITHIUM TITANIUM PHOSPHATE | - |
dc.subject.keywordPlus | IONIC-CONDUCTIVITY | - |
dc.subject.keywordPlus | SOLID ELECTROLYTES | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | CATION SIZE | - |
dc.subject.keywordPlus | TERNARY | - |
dc.subject.keywordPlus | SYSTEM | - |
dc.subject.keywordPlus | OXIDE | - |
dc.subject.keywordPlus | FRAMEWORKS | - |
dc.subject.keywordPlus | BATTERIES | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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