Balancing between Heterogeneity and Reactivity in Porphyrin Chromium-Cobaltate Catalyzed Ring Expansion Carbonylation of Epoxide into beta-Lactone
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Rajendiran, Senkuttuvan | - |
dc.contributor.author | Ganesan, Vinothkumar | - |
dc.contributor.author | Yoon, Sungho | - |
dc.date.accessioned | 2021-06-18T07:28:44Z | - |
dc.date.available | 2021-06-18T07:28:44Z | - |
dc.date.issued | 2019-03 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.issn | 1520-510X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/44843 | - |
dc.description.abstract | The synthesis of a unique heterogeneous catalyst that combines the functionality of a homogeneous catalyst and the advantages of a heterogeneous catalytic process is a continuing goal in various industrially applicable reactions. Here, we report heterogenization of homogeneous catalyst for lactone production from epoxide carbonylation through a facile polymerization using Friedel-Crafts reaction. A correlation between reactivity and degree of heterogeneity has been deduced by synthesizing different sized polymeric catalysts. The partially polymerized catalyst showed a remarkable initial turnover frequency of 400 h(-1), and the fully polymerized catalyst displayed excellent selectivity during recycling with a total turnover number of 4100. | - |
dc.format.extent | 7 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Balancing between Heterogeneity and Reactivity in Porphyrin Chromium-Cobaltate Catalyzed Ring Expansion Carbonylation of Epoxide into beta-Lactone | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/acs.inorgchem.8b03361 | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.58, no.5, pp 3283 - 3289 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000460600300043 | - |
dc.identifier.scopusid | 2-s2.0-85062426139 | - |
dc.citation.endPage | 3289 | - |
dc.citation.number | 5 | - |
dc.citation.startPage | 3283 | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 58 | - |
dc.type.docType | Article | - |
dc.publisher.location | 미국 | - |
dc.subject.keywordPlus | COVALENT TRIAZINE FRAMEWORK | - |
dc.subject.keywordPlus | PROPYLENE-OXIDE | - |
dc.subject.keywordPlus | POLYMERIZATION | - |
dc.subject.keywordPlus | ABSORPTION | - |
dc.subject.keywordPlus | FIXATION | - |
dc.subject.keywordPlus | CO2 | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
84, Heukseok-ro, Dongjak-gu, Seoul, Republic of Korea (06974)02-820-6194
COPYRIGHT 2019 Chung-Ang University All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.