A Metalated Porous Porphyrin Polymer with [Co(CO)(4)](-) Anion as an Efficient Heterogeneous Catalyst for Ring Expanding Carbonylation
DC Field | Value | Language |
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dc.contributor.author | Jiang, Jianwei | - |
dc.contributor.author | Yoon, Sungho | - |
dc.date.accessioned | 2021-06-18T07:32:32Z | - |
dc.date.available | 2021-06-18T07:32:32Z | - |
dc.date.issued | 2018-09 | - |
dc.identifier.issn | 2045-2322 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/45106 | - |
dc.description.abstract | The synthesis of beta-lactones from epoxides through ring-expanding carbonylation using homogeneous catalysts has received much attention. However, homogeneous catalysts suffer from difficulty in product separation and recycling of the catalyst, limiting their industrial usage. Herein, a novel heterogeneous catalyst, [Cr-metalated porous porphyrin polymer](+)[Co(CO)(4)](-), was prepared and used for the conversion of propylene oxide (PO) to beta-butyrolactone; this catalyst presented superior catalytic activity and selectivity (99%) than our previous heterogeneous catalyst. In addition, the catalyst was readily separated from the product without significant loss of catalytic activity. A possible method to recover the original catalytic activity also was demonstrated. | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | NATURE PUBLISHING GROUP | - |
dc.title | A Metalated Porous Porphyrin Polymer with [Co(CO)(4)](-) Anion as an Efficient Heterogeneous Catalyst for Ring Expanding Carbonylation | - |
dc.type | Article | - |
dc.identifier.doi | 10.1038/s41598-018-31475-6 | - |
dc.identifier.bibliographicCitation | SCIENTIFIC REPORTS, v.8 | - |
dc.description.isOpenAccess | Y | - |
dc.identifier.wosid | 000443745700025 | - |
dc.identifier.scopusid | 2-s2.0-85053000609 | - |
dc.citation.title | SCIENTIFIC REPORTS | - |
dc.citation.volume | 8 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordPlus | BETA-LACTONE SYNTHESIS | - |
dc.subject.keywordPlus | EPOXIDE CARBONYLATION | - |
dc.subject.keywordPlus | PROPYLENE-OXIDE | - |
dc.subject.keywordPlus | FRAMEWORK | - |
dc.subject.keywordPlus | CO | - |
dc.subject.keywordPlus | POLY(HYDROXYBUTYRATE) | - |
dc.subject.keywordPlus | BUTYROLACTONE | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | EXPANSION | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalWebOfScienceCategory | Multidisciplinary Sciences | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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