A heterogenized cobaltate catalyst on a bis-imidazolium-based covalent triazine framework for hydroesterification of epoxides
DC Field | Value | Language |
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dc.contributor.author | Rajendiran, Senkuttuvan | - |
dc.contributor.author | Gunasekar, Gunniya Hariyanandam | - |
dc.contributor.author | Yoon, Sungho | - |
dc.date.accessioned | 2021-06-18T07:42:07Z | - |
dc.date.available | 2021-06-18T07:42:07Z | - |
dc.date.issued | 2018-07 | - |
dc.identifier.issn | 1144-0546 | - |
dc.identifier.issn | 1369-9261 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/45229 | - |
dc.description.abstract | An imidazolium-cobaltate-based heterogeneous catalyst exhibits advantages over its homogeneous counterpart in the synthesis of -hydroxyesters from epoxides. However, leaching of cobaltate from the catalytic support decreases the selectivity and recyclability of the catalyst. To overcome such drawbacks, a bis-imidazolium-based covalent triazine framework (CTF) is employed as a catalytic support for the hydroesterification catalyst to reduce cobaltate leaching by the intramolecular anion stabilization effect of the multi-imidazolium moiety, resulting in an excellent selectivity for the -hydroxyester and unprecedented recyclability. | - |
dc.format.extent | 7 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | A heterogenized cobaltate catalyst on a bis-imidazolium-based covalent triazine framework for hydroesterification of epoxides | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/c8nj02292e | - |
dc.identifier.bibliographicCitation | NEW JOURNAL OF CHEMISTRY, v.42, no.14, pp 12256 - 12262 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000438394800120 | - |
dc.identifier.scopusid | 2-s2.0-85049755391 | - |
dc.citation.endPage | 12262 | - |
dc.citation.number | 14 | - |
dc.citation.startPage | 12256 | - |
dc.citation.title | NEW JOURNAL OF CHEMISTRY | - |
dc.citation.volume | 42 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordPlus | BETA-HYDROXYBUTYRATE | - |
dc.subject.keywordPlus | IONIC LIQUIDS | - |
dc.subject.keywordPlus | SUPPORTED PALLADIUM | - |
dc.subject.keywordPlus | ALZHEIMERS-DISEASE | - |
dc.subject.keywordPlus | PROPYLENE-OXIDE | - |
dc.subject.keywordPlus | RING-EXPANSION | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | CARBONYLATION | - |
dc.subject.keywordPlus | CO2 | - |
dc.subject.keywordPlus | 3-HYDROXYBUTYRATE | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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