Exceptionally stable Rh-based molecular catalyst heterogenized on a cationically charged covalent triazine framework support for efficient methanol carbonylation
DC Field | Value | Language |
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dc.contributor.author | Park, Kwangho | - |
dc.contributor.author | Lim, Sangyup | - |
dc.contributor.author | Baik, Joon Hyun | - |
dc.contributor.author | Kim, Honggon | - |
dc.contributor.author | Jung, Kwang-Deog | - |
dc.contributor.author | Yoon, Sungho | - |
dc.date.accessioned | 2021-06-18T07:42:20Z | - |
dc.date.available | 2021-06-18T07:42:20Z | - |
dc.date.issued | 2018-06 | - |
dc.identifier.issn | 2044-4753 | - |
dc.identifier.issn | 2044-4761 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/45245 | - |
dc.description.abstract | Direct carbonylation of methanol into methyl acetate and acetic acid using Rh-based heterogeneous catalysts is of great interest due to their effective levels of activity and stability. Here, a Rh-based molecular catalyst heterogenized on a charged 1,3-bis(pyridyl)imidazolium-based covalent triazine framework (Rh-bpim-CTF) was synthesized and characterized to have a single-site distribution of metal molecular species throughout the support by its ligation to abundant N atom sites. Methanol carbonylation was performed using the Rh-bpim-CTF catalyst in a plug-flow reaction in the gas phase, affording a turnover frequency of up to 3693 h(-1) and a productivity of 218.9 mol kg(-1) h(-1) for acetyl products with high stability. | - |
dc.format.extent | 7 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Exceptionally stable Rh-based molecular catalyst heterogenized on a cationically charged covalent triazine framework support for efficient methanol carbonylation | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/c8cy00294k | - |
dc.identifier.bibliographicCitation | CATALYSIS SCIENCE & TECHNOLOGY, v.8, no.11, pp 2894 - 2900 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000434386000016 | - |
dc.identifier.scopusid | 2-s2.0-85048419722 | - |
dc.citation.endPage | 2900 | - |
dc.citation.number | 11 | - |
dc.citation.startPage | 2894 | - |
dc.citation.title | CATALYSIS SCIENCE & TECHNOLOGY | - |
dc.citation.volume | 8 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordPlus | METHYL ACETATE | - |
dc.subject.keywordPlus | ACETIC-ACID | - |
dc.subject.keywordPlus | DIMETHYL ETHER | - |
dc.subject.keywordPlus | LIQUID-PHASE | - |
dc.subject.keywordPlus | TRANSFER HYDROGENATION | - |
dc.subject.keywordPlus | REACTION-MECHANISM | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | CO2 CAPTURE | - |
dc.subject.keywordPlus | FORMIC-ACID | - |
dc.subject.keywordPlus | RHODIUM | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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