Preparation of covalent triazine frameworks with imidazolium cations embedded in basic sites and their application for CO2 capture
DC Field | Value | Language |
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dc.contributor.author | Park, Kwangho | - |
dc.contributor.author | Lee, Kwangyeol | - |
dc.contributor.author | Kim, Hyunuk | - |
dc.contributor.author | Ganesan, Vinothkumar | - |
dc.contributor.author | Cho, Kanghee | - |
dc.contributor.author | Jeong, Soon Kwan | - |
dc.contributor.author | Yoon, Sungho | - |
dc.date.accessioned | 2021-06-18T08:42:48Z | - |
dc.date.available | 2021-06-18T08:42:48Z | - |
dc.date.issued | 2017-05 | - |
dc.identifier.issn | 2050-7488 | - |
dc.identifier.issn | 2050-7496 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/45566 | - |
dc.description.abstract | Functionalized covalent triazine frameworks (CTFs) realized by rational design of the monomer have been recognized as a promising candidate to achieve improvements in various applications. Here, new CTFs, 1,3-bis(pyridyl) imidazolium-based CTFs (bpim-CTFs), have been prepared via incorporation of an imidazolium motif into the monomer, which resulted in high functionalization of the frameworks. The bpim-CTFs showed N-rich environments, excellent micro-porosity (up to 1550 m(2) g(-1)) and high thermal stabilities, promising for efficient CO2 capture. The bpim-CTF-500 showed the highest CO2 uptake capacity of up to 2.77 mmol at 1 bar at a temperature of 298 K, which is higher than those of most of the other POFs except a few examples. Additionally, the frameworks featured moderate CO2 selectivity over N-2 up to 32. | - |
dc.format.extent | 7 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Preparation of covalent triazine frameworks with imidazolium cations embedded in basic sites and their application for CO2 capture | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/c6ta11226a | - |
dc.identifier.bibliographicCitation | JOURNAL OF MATERIALS CHEMISTRY A, v.5, no.18, pp 8576 - 8582 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000400983400044 | - |
dc.identifier.scopusid | 2-s2.0-85021637399 | - |
dc.citation.endPage | 8582 | - |
dc.citation.number | 18 | - |
dc.citation.startPage | 8576 | - |
dc.citation.title | JOURNAL OF MATERIALS CHEMISTRY A | - |
dc.citation.volume | 5 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordPlus | N-HETEROCYCLIC CARBENES | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | ORGANIC FRAMEWORKS | - |
dc.subject.keywordPlus | GAS-STORAGE | - |
dc.subject.keywordPlus | POLYMER NETWORKS | - |
dc.subject.keywordPlus | LINKED POLYMERS | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | SEPARATION | - |
dc.subject.keywordPlus | IMPACT | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Energy & Fuels | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Energy & Fuels | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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