Bis(4,4''-difluoro-1,1':3',1''-terphenyl-2'-carboxylato-κO) tetrakis(methanol-κO)calcium methanol tetrasolvate
DC Field | Value | Language |
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dc.contributor.author | Kim, Namseok | - |
dc.contributor.author | Noh, Heeso | - |
dc.contributor.author | Yoon, Sungho | - |
dc.contributor.author | Park, Chan Ryang | - |
dc.date.accessioned | 2021-06-18T09:42:40Z | - |
dc.date.available | 2021-06-18T09:42:40Z | - |
dc.date.issued | 2013-02 | - |
dc.identifier.issn | 1600-5368 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/45872 | - |
dc.description.abstract | In the title compound, [Ca(C19H11F2O 2)2(CH3OH)4]·4CH3OH, the Ca2+ ion is located on an inversion centre and is hexacoordinated by two O atoms of two 4,4''-difluoro-1,1':3',1''-terphenyl-2'-carboxylate ligands and four O atoms of four methanol ligands, forming a CaO6 polyhedron with a slightly distorted octahedral coordination geometry. The Ca - O - C angle between the carboxylate group and the calcium ion is 171.8 (2)°. Two types of intermolecular hydrogen-bond interactions (C=O⋯H and O - H⋯O) between the carboxylate ligand, the methanol solvent molecules and the coordinating methanol ligands generate a two-dimensional network parallel to (001). | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.title | Bis(4,4''-difluoro-1,1':3',1''-terphenyl-2'-carboxylato-κO) tetrakis(methanol-κO)calcium methanol tetrasolvate | - |
dc.type | Article | - |
dc.identifier.doi | 10.1107/S1600536813000044 | - |
dc.identifier.bibliographicCitation | Acta Crystallographica Section E: Structure Reports Online, v.69, no.2, pp m122 - m123 | - |
dc.description.isOpenAccess | Y | - |
dc.identifier.scopusid | 2-s2.0-84873380317 | - |
dc.citation.endPage | m123 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | m122 | - |
dc.citation.title | Acta Crystallographica Section E: Structure Reports Online | - |
dc.citation.volume | 69 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordAuthor | data-to-parameter ratio = 19.0 | - |
dc.subject.keywordAuthor | mean σ(C-C) = 0.004 Å | - |
dc.subject.keywordAuthor | R factor = 0.064 | - |
dc.subject.keywordAuthor | single-crystal X-ray study | - |
dc.subject.keywordAuthor | T = 200 K | - |
dc.subject.keywordAuthor | wR factor = 0.165 | - |
dc.description.journalRegisteredClass | scopus | - |
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