Cycloidal Magnetic Order Promoted by Labile Mixed Anionic Paths in M2(SeO3)F2(M = Mn2+, Ni2+)
DC Field | Value | Language |
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dc.contributor.author | Zhu, T. | - |
dc.contributor.author | Mentré, O. | - |
dc.contributor.author | Yang, H. | - |
dc.contributor.author | Jin, Y. | - |
dc.contributor.author | Zhang, X. | - |
dc.contributor.author | Arévalo-López, Á.M. | - |
dc.contributor.author | Ritter, C. | - |
dc.contributor.author | Choi, K.-Y. | - |
dc.contributor.author | Lü, M. | - |
dc.date.accessioned | 2021-09-16T02:40:25Z | - |
dc.date.available | 2021-09-16T02:40:25Z | - |
dc.date.issued | 2021-08-16 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.issn | 1520-510X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/49166 | - |
dc.description.abstract | Two M2(SeO3)F2 fluoro-selenites (M = Mn2+, Ni2+) have been synthesized using optimized hydrothermal reactions. Their 3D framework consists of 1D-[MO2F2]4-chains of edge-sharing octahedra with a rare topology of alternating O-O and F-F μ2 bridges. The interchain corner-sharing connections are assisted by the mixed O vs F anionic nature and develop a complex set of M-X-M superexchanges as calculated by LDA+U. Their interplay induces prominent in-chain antiferromagnetic frustration, while the interchain exchanges are responsible for the cycloidal magnetic structure observed below TN ≈ 21.5 K in the Ni2+ case. For comparison the Mn2+ compound develops a nearly collinear spin (canted) ordering below TN ≈ 26 K with ferromagnetic chain units. © 2021 American Chemical Society. | - |
dc.format.extent | 8 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | American Chemical Society | - |
dc.title | Cycloidal Magnetic Order Promoted by Labile Mixed Anionic Paths in M2(SeO3)F2(M = Mn2+, Ni2+) | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/acs.inorgchem.1c01074 | - |
dc.identifier.bibliographicCitation | Inorganic Chemistry, v.60, no.16, pp 12001 - 12008 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000687044700035 | - |
dc.identifier.scopusid | 2-s2.0-85112685793 | - |
dc.citation.endPage | 12008 | - |
dc.citation.number | 16 | - |
dc.citation.startPage | 12001 | - |
dc.citation.title | Inorganic Chemistry | - |
dc.citation.volume | 60 | - |
dc.type.docType | Article | - |
dc.publisher.location | 미국 | - |
dc.subject.keywordPlus | RAY PHOTOELECTRON-SPECTROSCOPY | - |
dc.subject.keywordPlus | TOTAL-ENERGY CALCULATIONS | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | CO | - |
dc.subject.keywordPlus | FLUOROPHOSPHATES | - |
dc.subject.keywordPlus | METAL | - |
dc.subject.keywordPlus | FE | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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