Anisotropic Li+ ion conductivity in a large single crystal of a Co(III) coordination complex
DC Field | Value | Language |
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dc.contributor.author | Kim, Saet Byeol | - |
dc.contributor.author | Kim, Jeung Yoon | - |
dc.contributor.author | Jeong, Nak Cheon | - |
dc.contributor.author | Ok, Kang Min | - |
dc.date.available | 2019-03-08T09:38:36Z | - |
dc.date.issued | 2017-01 | - |
dc.identifier.issn | 2052-1553 | - |
dc.identifier.issn | 2052-1553 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/4923 | - |
dc.description.abstract | Large single crystals of a novel lithium cobalt coordination compound, LiCo(NC5H3(CO2)(2))(2)(H2O)(2.125) [LiCo(PDC)(2)] were grown via a hydrothermal reaction in high yield. The electrochemical impedance spectroscopy (EIS) data measured on a large single crystal of LiCo(PDC)(2) revealed very interesting anisotropic Li+ ion conductivity. The redox potential for Co3+/Co4+ observed at ca. 200 mV in the cyclic voltammogram was consistent with the electric potential where the ionic conductivity occurred. Detailed structural analysis on a series of stoichiometrically equivalent cobalt coordination compounds, ACo(PDC)(2) (A = Na+, K+, and H3O+), indicated that the presence of ion channels as well as a suitable cation size is critical for the anisotropic ionic conductivity. | - |
dc.format.extent | 5 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Anisotropic Li+ ion conductivity in a large single crystal of a Co(III) coordination complex | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/c6qi00314a | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY FRONTIERS, v.4, no.1, pp 79 - 83 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000393814600006 | - |
dc.identifier.scopusid | 2-s2.0-85009350155 | - |
dc.citation.endPage | 83 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 79 | - |
dc.citation.title | INORGANIC CHEMISTRY FRONTIERS | - |
dc.citation.volume | 4 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORKS | - |
dc.subject.keywordPlus | PROTON CONDUCTIVITY | - |
dc.subject.keywordPlus | LITHIUM BATTERIES | - |
dc.subject.keywordPlus | PLASTIC CRYSTAL | - |
dc.subject.keywordPlus | ELECTROLYTES | - |
dc.subject.keywordPlus | TRANSPORT | - |
dc.subject.keywordPlus | POLYMERS | - |
dc.subject.keywordPlus | ENHANCEMENT | - |
dc.subject.keywordPlus | CONDUCTORS | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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