Synthesis and analysis of thermally degradable polybutadiene containing Diels-Alder adduct
DC Field | Value | Language |
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dc.contributor.author | Chang, Sanghoon | - |
dc.contributor.author | Kim, Yongkyun | - |
dc.contributor.author | Park, Haneul | - |
dc.contributor.author | Park, Kwangyong | - |
dc.date.accessioned | 2021-10-13T02:40:29Z | - |
dc.date.available | 2021-10-13T02:40:29Z | - |
dc.date.issued | 2021-12 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.issn | 1229-5949 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/50171 | - |
dc.description.abstract | The thermoreversible Diels-Alder reaction, a type of stimuli-responsive reversible organic reaction, is attractive because its direction can be easily controlled. In this study, the cross-linked Diels-Alder adduct-containing polybutadiene (DAPBD) was synthesized by the S(N)2 reaction of bromine-terminated polybutadiene with a furan-bismaleimide Diels-Alder adduct, and their thermodegradable behavior was analyzed by thermogravimetric analysis. DAPBD was dissociated by the retro-Diels-Alder reaction and dissolved in chlorobenzene at 132 degrees C to generate furan-terminated polybutadiene (FTPB) and bismaleimide that were identified by H-1 NMR spectroscopy. This synthetic method using premade Diels-Alder adducts is expected to enhance the thermoreversibility of the materials by significantly increasing the concentration of the Diels-Alder adduct moieties in the final DAPBD. The polymerization performed at 35 degrees C will help widen the scope of the use of such materials. | - |
dc.format.extent | 8 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | 대한화학회 | - |
dc.title | Synthesis and analysis of thermally degradable polybutadiene containing Diels-Alder adduct | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/bkcs.12411 | - |
dc.identifier.bibliographicCitation | Bulletin of the Korean Chemical Society, v.42, no.12, pp 1602 - 1609 | - |
dc.identifier.kciid | ART002786119 | - |
dc.description.isOpenAccess | Y | - |
dc.identifier.wosid | 000701315000001 | - |
dc.identifier.scopusid | 2-s2.0-85115962006 | - |
dc.citation.endPage | 1609 | - |
dc.citation.number | 12 | - |
dc.citation.startPage | 1602 | - |
dc.citation.title | Bulletin of the Korean Chemical Society | - |
dc.citation.volume | 42 | - |
dc.type.docType | Article | - |
dc.publisher.location | 대한민국 | - |
dc.subject.keywordAuthor | cross-linked polybutadiene | - |
dc.subject.keywordAuthor | Diels-Alder adduct | - |
dc.subject.keywordAuthor | S(N)2 reaction | - |
dc.subject.keywordAuthor | thermally degradable | - |
dc.subject.keywordPlus | REVERSIBLE CROSS-LINKING | - |
dc.subject.keywordPlus | MECHANICAL-PROPERTIES | - |
dc.subject.keywordPlus | CURABLE ADHESIVES | - |
dc.subject.keywordPlus | POLYMERS | - |
dc.subject.keywordPlus | NETWORK | - |
dc.subject.keywordPlus | BEARING | - |
dc.subject.keywordPlus | RUBBER | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | MALEIMIDE | - |
dc.subject.keywordPlus | HYDROGELS | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
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