Induced Eye-detectable Blue Emission of Triazolyl Derivatives via Selective Photodecomposition of Chloroform under UV Irradiation at 365 nm
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Byoung-Kwan | - |
dc.contributor.author | Yoon, Jun Hee | - |
dc.contributor.author | Yoon, Sangwoon | - |
dc.contributor.author | Cho, Byoung-Ki | - |
dc.date.accessioned | 2022-02-07T01:43:11Z | - |
dc.date.available | 2022-02-07T01:43:11Z | - |
dc.date.issued | 2014-01 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.issn | 1229-5949 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/54837 | - |
dc.description.abstract | A bent-shape triazolyl derivative was synthesized via click chemistry, and its photophysical property was investigated in various solvents. In contrast to the invisible ultraviolet emission of other solutions, the chloroform solution exhibited a blue light emission at 460 nm. Furthermore, the blue fluorescence intensified as the UV exposure time at 365 nm increased. On the basis of H-1-NMR, pH paper, and acid-addition studies, we confirmed that chloroform was decomposed into HCl with the aid of the triazolyl derivative. The density functional theory calculations suggested that the eye-detectable blue fluorescence was attributed to an intramolecular charge transfer process of the protonated triazolyl derivative in the chloroform solution. | - |
dc.format.extent | 6 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Induced Eye-detectable Blue Emission of Triazolyl Derivatives via Selective Photodecomposition of Chloroform under UV Irradiation at 365 nm | - |
dc.type | Article | - |
dc.identifier.doi | 10.5012/bkcs.2014.35.1.135 | - |
dc.identifier.bibliographicCitation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.35, no.1, pp 135 - 140 | - |
dc.identifier.kciid | ART001846044 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000330682100022 | - |
dc.identifier.scopusid | 2-s2.0-84892932560 | - |
dc.citation.endPage | 140 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 135 | - |
dc.citation.title | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.volume | 35 | - |
dc.type.docType | Article | - |
dc.publisher.location | 독일 | - |
dc.subject.keywordAuthor | Fluorescence | - |
dc.subject.keywordAuthor | Chloroform photolysis | - |
dc.subject.keywordAuthor | Click chemistry | - |
dc.subject.keywordAuthor | Intramolecular charge transfer | - |
dc.subject.keywordAuthor | Protonation | - |
dc.subject.keywordPlus | CHARGE-TRANSFER | - |
dc.subject.keywordPlus | IONIC LIQUID | - |
dc.subject.keywordPlus | AGGREGATION | - |
dc.subject.keywordPlus | RECEPTOR | - |
dc.subject.keywordPlus | COMPLEX | - |
dc.subject.keywordPlus | DRIVEN | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
84, Heukseok-ro, Dongjak-gu, Seoul, Republic of Korea (06974)02-820-6194
COPYRIGHT 2019 Chung-Ang University All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.