Sustainable photoredox chemistry of a transient ternary complex: an unconventional approach toward trifluoromethylated hydroquinones
DC Field | Value | Language |
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dc.contributor.author | Lee, Da Seul | - |
dc.contributor.author | Soni, Vineet Kumar | - |
dc.contributor.author | Heo, Seunga | - |
dc.contributor.author | Hwang, Ho Seong | - |
dc.contributor.author | You, Youngmin | - |
dc.contributor.author | Cho, Eun Jin | - |
dc.date.accessioned | 2022-07-22T07:40:09Z | - |
dc.date.available | 2022-07-22T07:40:09Z | - |
dc.date.issued | 2022-08 | - |
dc.identifier.issn | 1463-9262 | - |
dc.identifier.issn | 1463-9270 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/58335 | - |
dc.description.abstract | A distinctive sustainable approach has been developed to afford highly functionalized CF3-hydroquinone derivatives as potent biologically active molecules. The synthetic protocol involves the photoirradiation of a mixture of easily accessible benzoquinones and CF3SO2Na. This process generates a quinhydrone charge-transfer complex of benzoquinone and its in situ generated hydroquinone in the presence of a small amount of hydrogen donors, more preferably water. The subsequent formation of a transient ternary complex involving CF3SO2Na elicits photoinduced charge-transfer (CT), thereby producing CF3-hydroquinones. The present method is highly practical and atom-economical whilst avoiding the use of any sacrificial electron donors. Furthermore, the unique ternary complex intermediate permits site-selective three-component trifluoromethylation in the presence of vinyl arenes. | - |
dc.format.extent | 6 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Sustainable photoredox chemistry of a transient ternary complex: an unconventional approach toward trifluoromethylated hydroquinones | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/d2gc01691e | - |
dc.identifier.bibliographicCitation | GREEN CHEMISTRY, v.24, no.17, pp 6481 - 6486 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000813556900001 | - |
dc.identifier.scopusid | 2-s2.0-85132724305 | - |
dc.citation.endPage | 6486 | - |
dc.citation.number | 17 | - |
dc.citation.startPage | 6481 | - |
dc.citation.title | GREEN CHEMISTRY | - |
dc.citation.volume | 24 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordPlus | C-H TRIFLUOROMETHYLATION | - |
dc.subject.keywordPlus | DONOR-ACCEPTOR COMPLEX | - |
dc.subject.keywordPlus | OXIDATIVE TRIFLUOROMETHYLATION | - |
dc.subject.keywordPlus | LIGHT-IRRADIATION | - |
dc.subject.keywordPlus | ALKENES | - |
dc.subject.keywordPlus | HYDROTRIFLUOROMETHYLATION | - |
dc.subject.keywordPlus | CF3SO2NA | - |
dc.subject.keywordPlus | STYRENES | - |
dc.subject.keywordPlus | REAGENT | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Green & Sustainable Science & Technology | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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