Photocatalytic para-Selective C-H Functionalization of Anilines with Diazomalonates
DC Field | Value | Language |
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dc.contributor.author | Karmakar, Ujjwal | - |
dc.contributor.author | Hwang, Ho Seong | - |
dc.contributor.author | Lee, Yunjeong | - |
dc.contributor.author | Cho, Eun Jin | - |
dc.date.accessioned | 2022-10-27T06:40:15Z | - |
dc.date.available | 2022-10-27T06:40:15Z | - |
dc.date.issued | 2022-08 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.issn | 1523-7052 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/58909 | - |
dc.description.abstract | Visible-light-induced para-selective C-H functionalization of anilines over N-H insertion was developed using diazomalonates with the help of an Ir(III) photocatalyst. The para-selective radical-radical cross coupling proceeded via C-centered radical intermediates generated from both anilines and diazomalonates. The photochemistry of anilines could be extended to other N-heterocycles, such as indole and carbazole. The reaction pathway for the selective C-C coupling was validated by electrochemical and photophysical experiments as well as computational studies. © 2022 American Chemical Society. | - |
dc.format.extent | 5 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | American Chemical Society | - |
dc.title | Photocatalytic para-Selective C-H Functionalization of Anilines with Diazomalonates | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/acs.orglett.2c02228 | - |
dc.identifier.bibliographicCitation | Organic Letters, v.24, no.33, pp 6137 - 6141 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000860016100001 | - |
dc.identifier.scopusid | 2-s2.0-85136717581 | - |
dc.citation.endPage | 6141 | - |
dc.citation.number | 33 | - |
dc.citation.startPage | 6137 | - |
dc.citation.title | Organic Letters | - |
dc.citation.volume | 24 | - |
dc.type.docType | Article | - |
dc.publisher.location | 미국 | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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