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Cited 4 time in webofscience Cited 4 time in scopus
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A Polar Titanium-Organic Chain with a Very Large Second-Harmonic-Generation Response

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dc.contributor.authorKim, Bongsu-
dc.contributor.authorOh, Seung-Jin-
dc.contributor.authorJo, Hongil-
dc.contributor.authorOk, Kang Min-
dc.date.available2019-03-08T12:00:04Z-
dc.date.issued2016-11-
dc.identifier.issn0020-1669-
dc.identifier.issn1520-510X-
dc.identifier.urihttps://scholarworks.bwise.kr/cau/handle/2019.sw.cau/6440-
dc.description.abstractA noncentrosymmetric (NCS) titanium-organic compound, [H2N(CH3)(2)] TiO{[NC5H3(CO2)(2)] [NC5H4(CO2)]} (CAUMOF-18), has been synthesized by a solvothermal reaction. The aligned unidimensional polar chain structure of CAUMOF-18 consisting of corner-shared distorted TiO5N2 pentagonal bipyramids is attributed to strong hydrogen-bonding and pi-pi interactions. CAUMOF-18 reveals a very strong second harmonic -generation efficiency of 400 times that of alpha-SiO2 and is phase-matchable (type I). Water-molecule driven reversible centricity conversion and topotactic transformation to TiO2 microrods for CAUMOF-18 are also presented.-
dc.format.extent4-
dc.language영어-
dc.language.isoENG-
dc.publisherAMER CHEMICAL SOC-
dc.titleA Polar Titanium-Organic Chain with a Very Large Second-Harmonic-Generation Response-
dc.typeArticle-
dc.identifier.doi10.1021/acs.inorgchem.6b02536-
dc.identifier.bibliographicCitationINORGANIC CHEMISTRY, v.55, no.22, pp 11635 - 11638-
dc.description.isOpenAccessN-
dc.identifier.wosid000388548300006-
dc.identifier.scopusid2-s2.0-84997751464-
dc.citation.endPage11638-
dc.citation.number22-
dc.citation.startPage11635-
dc.citation.titleINORGANIC CHEMISTRY-
dc.citation.volume55-
dc.type.docTypeArticle-
dc.publisher.location미국-
dc.subject.keywordPlusNONLINEAR-OPTICAL MATERIALS-
dc.subject.keywordPlusCOORDINATION NETWORKS-
dc.subject.keywordPlusGENERATION RESPONSE-
dc.subject.keywordPlusNONCENTROSYMMETRIC MATERIALS-
dc.subject.keywordPlusCRYSTAL-STRUCTURE-
dc.subject.keywordPlusMETAL SELENITES-
dc.subject.keywordPlusSHG RESPONSES-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusCARBONATE-
dc.subject.keywordPlusFRAMEWORK-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Inorganic & Nuclear-
dc.description.journalRegisteredClasssci-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
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