Importance of Electron Transport Ability in Naphthalene Diimide-Based Polymer Acceptors for High-Performance, Additive-Free, All-Polymer Solar Cells
DC Field | Value | Language |
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dc.contributor.author | Choi, Joonhyeong | - |
dc.contributor.author | Kim, Ki-Hyun | - |
dc.contributor.author | Yu, Hojeong | - |
dc.contributor.author | Lee, Changyeon | - |
dc.contributor.author | Kang, Hyunbum | - |
dc.contributor.author | Song, Inho | - |
dc.contributor.author | Kim, Youngwoong | - |
dc.contributor.author | Oh, Joon Hak | - |
dc.contributor.author | Kim, Bumjoon J. | - |
dc.date.accessioned | 2023-03-08T18:43:08Z | - |
dc.date.available | 2023-03-08T18:43:08Z | - |
dc.date.issued | 2015-08 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.issn | 1520-5002 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/64498 | - |
dc.description.abstract | We report a systematic investigation of the correlations between the electron mobility of polymer acceptors and the photovoltaic performances of all-polymer solar cells (all-PSCs) by using a series of naphthalene diimide (NDI)-based polymer acceptors. Polymer acceptors typically have much lower electron mobility than fullerenes, which is one of the main factors in limiting the performance of all-PSCs. In addition, the anisotropic charge transport properties of the polymers require careful control of their packing structure and orientation suitable for their use in all-PSCs. To control the planarity of the polymer backbone and enhance electron mobility, we introduce three different electron-rich units (i.e., thiophene (T), bithiophene (T2), and thienylene-vinylene-thienylene (TVT)) into the NDI-based polymers. Particularly, P(NDI2OD-TVT) polymers exhibit the highest electron mobility (2.31 cm(2) V-1 s(-1)) in organic field-effect transistors owing to various factors including enhanced degree of coplanarity, strong intermolecular interactions, and facilitated three-dimensional (3-D) charge transport. In addition, the superb electron transport capability of P(NDI2OD-TVT) leads to a well-balanced hole/electron mobility ratio in all-PSC blends. Thus, all-PSCs based on the P(NDI2OD-TVT) acceptor exhibit a high power conversion efficiency of 4.25% without any solvent additives or thermal treatments. We suggest that the high electron transport ability of the polymer acceptor is important requirement for producing high-performance, additive-free all-PSCs. | - |
dc.format.extent | 8 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Importance of Electron Transport Ability in Naphthalene Diimide-Based Polymer Acceptors for High-Performance, Additive-Free, All-Polymer Solar Cells | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/acs.chemmater.5b01274 | - |
dc.identifier.bibliographicCitation | CHEMISTRY OF MATERIALS, v.27, no.15, pp 5230 - 5237 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000359499100011 | - |
dc.identifier.scopusid | 2-s2.0-84939208993 | - |
dc.citation.endPage | 5237 | - |
dc.citation.number | 15 | - |
dc.citation.startPage | 5230 | - |
dc.citation.title | CHEMISTRY OF MATERIALS | - |
dc.citation.volume | 27 | - |
dc.type.docType | Article | - |
dc.publisher.location | 미국 | - |
dc.subject.keywordPlus | POWER CONVERSION EFFICIENCY | - |
dc.subject.keywordPlus | FIELD-EFFECT TRANSISTORS | - |
dc.subject.keywordPlus | CONJUGATED POLYMERS | - |
dc.subject.keywordPlus | CHARGE-TRANSPORT | - |
dc.subject.keywordPlus | BLEND MORPHOLOGY | - |
dc.subject.keywordPlus | SIDE-CHAINS | - |
dc.subject.keywordPlus | COPOLYMER | - |
dc.subject.keywordPlus | SELENOPHENE | - |
dc.subject.keywordPlus | AGGREGATION | - |
dc.subject.keywordPlus | BENZODITHIOPHENE | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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