Facile fabrication of porous Sn-based catalysts for electrochemical CO2 reduction to HCOOH and syngas
DC Field | Value | Language |
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dc.contributor.author | Kim, Hyenki | - |
dc.contributor.author | Lee, Hyunju | - |
dc.contributor.author | Lim, Taeho | - |
dc.contributor.author | Ahn, Sang Hyun | - |
dc.date.available | 2019-01-22T12:34:22Z | - |
dc.date.issued | 2018-10 | - |
dc.identifier.issn | 1226-086X | - |
dc.identifier.issn | 1876-794X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/647 | - |
dc.description.abstract | Porous Sn and Sn-based binary catalysts are facilely fabricated by an electrodeposition method. Varying conditions for Sn electrodeposition enables a control of Sn roughness, which exhibits a significant effect on catalytic performance for electrochemical CO2 reduction. At a specific applied potential, the porous Sn catalyst with relative roughness factor of 56.5 demonstrates a HCOOH Faradaic efficiency of 40.7% with a H-2/CO ratio of 2.2. Further improvement of the HCOOH Faradaic efficiency to 59.2% is achieved by using a porous Sn0.29In0.71 catalyst. This catalyst also achieves a H-2/CO ratio of 2.2, which can be used as syngas to produce value-added hydrocarbons. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved. | - |
dc.format.extent | 6 | - |
dc.publisher | ELSEVIER SCIENCE INC | - |
dc.title | Facile fabrication of porous Sn-based catalysts for electrochemical CO2 reduction to HCOOH and syngas | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.jiec.2018.05.036 | - |
dc.identifier.bibliographicCitation | JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, v.66, pp 248 - 253 | - |
dc.identifier.kciid | ART002396925 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000446144400024 | - |
dc.identifier.scopusid | 2-s2.0-85048739753 | - |
dc.citation.endPage | 253 | - |
dc.citation.startPage | 248 | - |
dc.citation.title | JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | - |
dc.citation.volume | 66 | - |
dc.type.docType | Article | - |
dc.publisher.location | 대한민국 | - |
dc.subject.keywordAuthor | Electrochemical CO2 reduction | - |
dc.subject.keywordAuthor | Foam structure | - |
dc.subject.keywordAuthor | Electrodeposition | - |
dc.subject.keywordAuthor | HCOOH | - |
dc.subject.keywordAuthor | Syngas | - |
dc.subject.keywordPlus | ACID FUEL-CELLS | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | FORMIC-ACID | - |
dc.subject.keywordPlus | HYDROGEN EVOLUTION | - |
dc.subject.keywordPlus | METAL-ELECTRODES | - |
dc.subject.keywordPlus | SELECTIVITY | - |
dc.subject.keywordPlus | SURFACES | - |
dc.subject.keywordPlus | FOAM | - |
dc.subject.keywordPlus | ELECTROCATALYSTS | - |
dc.subject.keywordPlus | CONVERSION | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
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