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Designing High-Performance PbS and PbSe Nanocrystal Electronic Devices through Stepwise, Post-Synthesis, Colloidal Atomic Layer Deposition

Authors
Oh, Soong JuBerry, Nathaniel E.Choi, Ji-HyukGaulding, E. AshleyLin, HangfeiPaik, TaejongDiroll, Benjamin T.Muramoto, ShinMurray, Christopher B.Kagan, Cherie R.
Issue Date
Mar-2014
Publisher
AMER CHEMICAL SOC
Keywords
Lead chalcogenide; nanocrystals; colloidal atomic layer deposition; stoichiometry; solution-process; field-effect transistor
Citation
NANO LETTERS, v.14, no.3, pp 1559 - 1566
Pages
8
Journal Title
NANO LETTERS
Volume
14
Number
3
Start Page
1559
End Page
1566
URI
https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/66741
DOI
10.1021/nl404818z
ISSN
1530-6984
1530-6992
Abstract
We report a simple, solution-based, postsynthetic colloidal, atomic layer deposition (PS-cALD) process to engineer stepwise the surface stoichiometry and therefore the electronic properties of lead chalcogenide nanocrystal (NC) thin films integrated in devices. We found that unlike chalcogen-enriched NC surfaces that are structurally, optically, and electronically unstable, lead chloride treatment creates a well-passivated shell that stabilizes the NCs. Using PS-cALD of lead chalcogenide NC thin films we demonstrate high electron field-effect mobilities of similar to 4.5 cm(2)/(V s).
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