Eco-compatible solvent-processed high energy level offset ternary strategy for efficient organic photodetecting and photovoltaic applications
- Authors
- Kim, Min Soo; Jang, Woongsik; Kim, Byung Gi; Wang, Dong Hwan
- Issue Date
- Jul-2023
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- JOURNAL OF MATERIALS CHEMISTRY C, v.11, no.26, pp 8776 - 8783
- Pages
- 8
- Journal Title
- JOURNAL OF MATERIALS CHEMISTRY C
- Volume
- 11
- Number
- 26
- Start Page
- 8776
- End Page
- 8783
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/67355
- DOI
- 10.1039/d3tc01527k
- ISSN
- 2050-7526
2050-7534
- Abstract
- We designed a ternary strategy for efficient and stable organic electronic devices (OEDs) by introducing high lowest unoccupied molecular orbital (LUMO) level 5,5 '-[[4,4,9,9-tetrakis(2-ethylhexyl)-4,9-dihydro-s-indaceno[1,2-b:5,6-b ']dithiophene-2,7-diyl]bis(2,1,3-benzothiadiazole-7,4-diylmethylidyne)]bis[3-ethyl-2-thioxo-4-thiazolidinone] (EH-IDTBR) as a third component acceptor. We investigated the photovoltaic and photodetection properties of the EH-IDTBR-ratio-dependent active-layer-based OED via current-voltage characteristics under both light and dark conditions using atomic force microscopy (AFM), trap density, impedance spectroscopy, and photoresponse speed measurements. Among the four types of active-layer-based devices, the optimized EH-IDTBR-ratio-based ternary device provided the most effective photoelectric conversion and dark current suppression properties. These desirable properties originate from the high energy level offset of EH-IDTBR, and also it has superior intermolecular charge transport and can withstand degradation by externally stimuli, such as oxidation and applied bias. We confirmed the anti-degradation behavior and resulting OED performance through various analyses.
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Collections - College of ICT Engineering > School of Integrative Engineering > 1. Journal Articles
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