Ni-catalyzed regioselective C-C bond formation of 1,1-disubstituted allenes with aldehydes
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Seoyeon | - |
dc.contributor.author | Kim, Jinyoung | - |
dc.contributor.author | Tambe, Shrikant D. | - |
dc.contributor.author | Cho, Eun Jin | - |
dc.date.accessioned | 2024-02-08T03:00:27Z | - |
dc.date.available | 2024-02-08T03:00:27Z | - |
dc.date.issued | 2024-01 | - |
dc.identifier.issn | 2052-4110 | - |
dc.identifier.issn | 2052-4129 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/71861 | - |
dc.description.abstract | Allenes, despite their structural resemblance to alkenes and alkynes, exhibit unique reactivity due to the orthogonal arrangement of their cumulative π-bonds, making precise allene selectivity an emerging area of interest. Previous studies on Ni-catalyzed coupling reactions between allenes and aldehydes yielded diverse regioselectivities, with nucleophilic and reductive conditions producing different outcomes. In this work, we developed a regioselective method for generating linear products through coupling at the terminal carbon of 1,1-disubstituted allenes using photoredox/Ni-dual catalysis. We achieved the regioselectivity by strategically modifying substrate patterns and the catalytic system employing an unconventional P^N ligand. This work represents a notable advancement in selective catalysis, offering valuable insights into the control of allene reactivity. © 2024 The Royal Society of Chemistry. | - |
dc.format.extent | 6 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | Royal Society of Chemistry | - |
dc.title | Ni-catalyzed regioselective C-C bond formation of 1,1-disubstituted allenes with aldehydes | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/d3qo01800h | - |
dc.identifier.bibliographicCitation | Organic Chemistry Frontiers, v.11, no.3, pp 816 - 821 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 001125301600001 | - |
dc.identifier.scopusid | 2-s2.0-85180307681 | - |
dc.citation.endPage | 821 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 816 | - |
dc.citation.title | Organic Chemistry Frontiers | - |
dc.citation.volume | 11 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordPlus | CHIRAL P,N-LIGANDS | - |
dc.subject.keywordPlus | NICKEL | - |
dc.subject.keywordPlus | PHOTOREDOX | - |
dc.subject.keywordPlus | ACCESS | - |
dc.subject.keywordPlus | SELECTIVITY | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | ALKYNES | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
84, Heukseok-ro, Dongjak-gu, Seoul, Republic of Korea (06974)02-820-6194
COPYRIGHT 2019 Chung-Ang University All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.