Visible-Light-Promoted Synthesis of Fluoroalkylated Oximes
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Da Seul | - |
dc.contributor.author | Hwang, Ho Seong | - |
dc.contributor.author | Cho, Eun Jin | - |
dc.date.available | 2019-01-22T12:38:16Z | - |
dc.date.issued | 2018-09 | - |
dc.identifier.issn | 1861-4728 | - |
dc.identifier.issn | 1861-471X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/802 | - |
dc.description.abstract | A method has been developed for the synthesis of fluoroalkylated oximes, potential fluoroalkyl building-blocks for the synthesis of various organofluorine compounds, from easily available amino substrates and fluoroalkylated alkenes. tBuONO was utilized both as a diazotizing agent and as a NO radical source for the oxime synthesis in the process, and the use of a photocatalyst under visible-light irradiation increased the efficiency of the reaction. Various fluoroalkylated oximes were prepared by a tandem process of aryl radical addition to fluoroalkylated alkene and consecutive oxime generation process, albeit in moderate yields. This differentiated approach, transferring an aromatic system into an electron-deficient fluoroalkylated alkene, expands the scope of substrates where electron-poor aromatic systems could be utilized. | - |
dc.format.extent | 5 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Visible-Light-Promoted Synthesis of Fluoroalkylated Oximes | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/asia.201800524 | - |
dc.identifier.bibliographicCitation | CHEMISTRY-AN ASIAN JOURNAL, v.13, no.17, pp 2405 - 2409 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000443679400026 | - |
dc.identifier.scopusid | 2-s2.0-85047736620 | - |
dc.citation.endPage | 2409 | - |
dc.citation.number | 17 | - |
dc.citation.startPage | 2405 | - |
dc.citation.title | CHEMISTRY-AN ASIAN JOURNAL | - |
dc.citation.volume | 13 | - |
dc.type.docType | Article | - |
dc.publisher.location | 독일 | - |
dc.subject.keywordAuthor | fluorine | - |
dc.subject.keywordAuthor | nitrites | - |
dc.subject.keywordAuthor | oximes | - |
dc.subject.keywordAuthor | photocatalysis | - |
dc.subject.keywordAuthor | radical reactions | - |
dc.subject.keywordPlus | PHOTOREDOX CATALYSIS | - |
dc.subject.keywordPlus | REGIOSELECTIVE SYNTHESIS | - |
dc.subject.keywordPlus | CONTINUOUS-FLOW | - |
dc.subject.keywordPlus | PYRIDINES | - |
dc.subject.keywordPlus | FLUORINE | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | ALKENES | - |
dc.subject.keywordPlus | TRIFLUOROMETHYLATION | - |
dc.subject.keywordPlus | PHENANTHRIDINES | - |
dc.subject.keywordPlus | CONDENSATION | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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