Synthesis of cyclopenta-fused polycyclic aromatic hydrocarbons utilizing aryl-substituted anilines
- Authors
- Choi, Yeojin; Chatterjee, Tanmay; Kim, Jun; Kim, Jun Soo; Cho, Eun Jin
- Issue Date
- Jul-2016
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- ORGANIC & BIOMOLECULAR CHEMISTRY, v.14, no.28, pp 6804 - 6810
- Pages
- 7
- Journal Title
- ORGANIC & BIOMOLECULAR CHEMISTRY
- Volume
- 14
- Number
- 28
- Start Page
- 6804
- End Page
- 6810
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/8704
- DOI
- 10.1039/c6ob01235c
- ISSN
- 1477-0520
1477-0539
- Abstract
- Cyclopenta-fused polycyclic aromatic hydrocarbons (CP-PAHs), potentially electronically and biologically highly active materials, were synthesized from readily available 2-aryl-substituted anilines. Reactions occur under extremely mild, room temperature conditions using (BuONO)-Bu-t as the sole reagent. The use of a nitrite source generates a reactive diazonium intermediate in situ that then reacts with a tethered polycyclic aromatic moiety by intramolecular aromatic substitution. This protocol could be presented as one of the simplest methods to access CP-PAHs.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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