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Cited 23 time in webofscience Cited 25 time in scopus
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Synthesis of beta-Trifluoromethylated Ketones from Propargylic Alcohols by Visible Light Photoredox Catalysis

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dc.contributor.authorPark, Sehyun-
dc.contributor.authorJoo, Jung Min-
dc.contributor.authorCho, Eun Jin-
dc.date.available2019-03-08T16:59:58Z-
dc.date.issued2015-07-
dc.identifier.issn1434-193X-
dc.identifier.issn1099-0690-
dc.identifier.urihttps://scholarworks.bwise.kr/cau/handle/2019.sw.cau/9386-
dc.description.abstractRegioselective trifluoromethylation at a remote position represents an important challenge in the development of biologically active molecules and functional materials. A practical method to access -trifluoromethyl ketones from readily available propargylic alcohols by visible light photocatalysis has been developed. Trifluoromethylation of propargylic alcohols with CF3I in the presence of Ru(bpy)(3)Cl-2 as the photocatalyst followed by double-bond migration/keto-enol tautomerization provides -trifluoromethyl ketones as the final product.-
dc.format.extent5-
dc.language영어-
dc.language.isoENG-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.titleSynthesis of beta-Trifluoromethylated Ketones from Propargylic Alcohols by Visible Light Photoredox Catalysis-
dc.typeArticle-
dc.identifier.doi10.1002/ejoc.201500031-
dc.identifier.bibliographicCitationEUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2015, no.19, pp 4093 - 4097-
dc.description.isOpenAccessN-
dc.identifier.wosid000356870600006-
dc.identifier.scopusid2-s2.0-85027922215-
dc.citation.endPage4097-
dc.citation.number19-
dc.citation.startPage4093-
dc.citation.titleEUROPEAN JOURNAL OF ORGANIC CHEMISTRY-
dc.citation.volume2015-
dc.type.docTypeArticle-
dc.publisher.location독일-
dc.subject.keywordAuthorPhotocatalysis-
dc.subject.keywordAuthorRadical reactions-
dc.subject.keywordAuthorTrifluoromethylation-
dc.subject.keywordAuthorPropargylic alcohols-
dc.subject.keywordAuthorKetones-
dc.subject.keywordPlusSILYL ENOL ETHERS-
dc.subject.keywordPlusRADICAL TRIFLUOROMETHYLATION-
dc.subject.keywordPlusALLYLIC ALCOHOLS-
dc.subject.keywordPlusREGIOSELECTIVE 1,4-TRIFLUOROMETHYLATION-
dc.subject.keywordPlusNUCLEOPHILIC TRIFLUOROMETHYLATION-
dc.subject.keywordPlusSUBSTITUTED KETONES-
dc.subject.keywordPlusFACILE SYNTHESIS-
dc.subject.keywordPlusATE ENOLATE-
dc.subject.keywordPlusALPHA-
dc.subject.keywordPlusALKENES-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.description.journalRegisteredClasssci-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
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