Synthesis of beta-Trifluoromethylated Ketones from Propargylic Alcohols by Visible Light Photoredox Catalysis
DC Field | Value | Language |
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dc.contributor.author | Park, Sehyun | - |
dc.contributor.author | Joo, Jung Min | - |
dc.contributor.author | Cho, Eun Jin | - |
dc.date.available | 2019-03-08T16:59:58Z | - |
dc.date.issued | 2015-07 | - |
dc.identifier.issn | 1434-193X | - |
dc.identifier.issn | 1099-0690 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/9386 | - |
dc.description.abstract | Regioselective trifluoromethylation at a remote position represents an important challenge in the development of biologically active molecules and functional materials. A practical method to access -trifluoromethyl ketones from readily available propargylic alcohols by visible light photocatalysis has been developed. Trifluoromethylation of propargylic alcohols with CF3I in the presence of Ru(bpy)(3)Cl-2 as the photocatalyst followed by double-bond migration/keto-enol tautomerization provides -trifluoromethyl ketones as the final product. | - |
dc.format.extent | 5 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Synthesis of beta-Trifluoromethylated Ketones from Propargylic Alcohols by Visible Light Photoredox Catalysis | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/ejoc.201500031 | - |
dc.identifier.bibliographicCitation | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2015, no.19, pp 4093 - 4097 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000356870600006 | - |
dc.identifier.scopusid | 2-s2.0-85027922215 | - |
dc.citation.endPage | 4097 | - |
dc.citation.number | 19 | - |
dc.citation.startPage | 4093 | - |
dc.citation.title | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | - |
dc.citation.volume | 2015 | - |
dc.type.docType | Article | - |
dc.publisher.location | 독일 | - |
dc.subject.keywordAuthor | Photocatalysis | - |
dc.subject.keywordAuthor | Radical reactions | - |
dc.subject.keywordAuthor | Trifluoromethylation | - |
dc.subject.keywordAuthor | Propargylic alcohols | - |
dc.subject.keywordAuthor | Ketones | - |
dc.subject.keywordPlus | SILYL ENOL ETHERS | - |
dc.subject.keywordPlus | RADICAL TRIFLUOROMETHYLATION | - |
dc.subject.keywordPlus | ALLYLIC ALCOHOLS | - |
dc.subject.keywordPlus | REGIOSELECTIVE 1,4-TRIFLUOROMETHYLATION | - |
dc.subject.keywordPlus | NUCLEOPHILIC TRIFLUOROMETHYLATION | - |
dc.subject.keywordPlus | SUBSTITUTED KETONES | - |
dc.subject.keywordPlus | FACILE SYNTHESIS | - |
dc.subject.keywordPlus | ATE ENOLATE | - |
dc.subject.keywordPlus | ALPHA | - |
dc.subject.keywordPlus | ALKENES | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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