Zero Energy Heating of Solvent with Network-Structured Solar-Thermal Material: Eco-Friendly Palladium Catalysis of the Suzuki Reaction
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, Seungbeom | - |
dc.contributor.author | Park, Woomin | - |
dc.contributor.author | Lee, Kangjoo | - |
dc.contributor.author | Min, Sun-Joon | - |
dc.contributor.author | Jang, Kwang-Suk | - |
dc.date.accessioned | 2023-02-21T05:38:42Z | - |
dc.date.available | 2023-02-21T05:38:42Z | - |
dc.date.created | 2023-02-01 | - |
dc.date.issued | 2022-08 | - |
dc.identifier.issn | 1944-8244 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/111534 | - |
dc.description.abstract | Solar-thermal materials absorb sunlight and convert it into heat, which is released into the surrounding medium. Utilization of solar energy for solvent heating can be a potential method of eco-friendly organic reactions. However, to date, significant heating of the entire volume of a solvent by 1 sun illumination has not been reported. In the present work, a network structure of solar-thermal materials has been proposed for zero energy heating of a solvent under 1 sun illumination. A network-structured solar-thermal material with an additional catalytic function was fabricated by sputtering palladium into a melamine sponge. The nanocrystalline palladium-decorated melamine sponge (Pd-sponge) has excellent sunlight absorption properties in the entire wavelength range that enable efficient solar-thermal conversion. The Pd-sponge can reduce heat loss to the surroundings by effectively blocking thermal radiation from the heated solvent. The temperature of the reaction solution with the ethanol-water mixture filled in the Pd-sponge increased from 23 to 59 degrees C under 1 sun illumination. The elevated temperature of the reaction solutions by solar-thermal conversion successfully accelerated the heterogeneous Pd-catalyzed Suzuki coupling reactions with high conversions. Easy and low-energy-consuming multicycle use of the solar-thermal and catalytic properties of the Pd-sponge has also been demonstrated. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Zero Energy Heating of Solvent with Network-Structured Solar-Thermal Material: Eco-Friendly Palladium Catalysis of the Suzuki Reaction | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Min, Sun-Joon | - |
dc.contributor.affiliatedAuthor | Jang, Kwang-Suk | - |
dc.identifier.doi | 10.1021/acsami.2c10530 | - |
dc.identifier.scopusid | 2-s2.0-85137877930 | - |
dc.identifier.wosid | 000855228000001 | - |
dc.identifier.bibliographicCitation | ACS APPLIED MATERIALS & INTERFACES | - |
dc.relation.isPartOf | ACS APPLIED MATERIALS & INTERFACES | - |
dc.citation.title | ACS APPLIED MATERIALS & INTERFACES | - |
dc.type.rims | ART | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | CROSS-COUPLING REACTION | - |
dc.subject.keywordPlus | 1-ALKENYLBORANES | - |
dc.subject.keywordPlus | THERAPY | - |
dc.subject.keywordAuthor | solar-thermal effect | - |
dc.subject.keywordAuthor | network structure | - |
dc.subject.keywordAuthor | eco-friendly reaction | - |
dc.subject.keywordAuthor | Pd catalyst | - |
dc.subject.keywordAuthor | Suzuki reaction | - |
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