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Surface-crosslinking in the presence of nanoclay and characteristics of the itaconic acid-based superabsorbent polymer composites

Authors
Kim, Hae ChanKwon, Yong RokKim, Jung SooKim, Jong-HoKim, Dong Hyun
Issue Date
Apr-2023
Publisher
TAYLOR & FRANCIS INC
Keywords
Superabsorbent polymer; nanoclay; surface-crosslinking; itaconic acid; absorption properties
Citation
Polymer-plastics Technology and Materials, v.62, no.6, pp 701 - 711
Pages
11
Indexed
SCIE
SCOPUS
Journal Title
Polymer-plastics Technology and Materials
Volume
62
Number
6
Start Page
701
End Page
711
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/112652
DOI
10.1080/25740881.2022.2133613
ISSN
2574-0881
Abstract
Herein, the absorption properties of a superabsorbent polymer (SAP) are enhanced by preparing a lightly crosslinked poly(itaconic acid-co-acrylic acid) via solution copolymerization with 1,6-hexanediol acrylate as the crosslinker and ammonium persulfate as the initiator, then adding a surface-crosslinked shell containing a nanoclay. The structures of the CSAP and surface-crosslinked SAP are characterized using FT-IR spectroscopy and XRD analysis. The analysis in absorption properties according to nanoclay are evaluated. In addition, the gel strength and thermal stability are evaluated. The introduction of nanoclay in the surface layer is thereby shown to improve the absorption properties and thermal stability of the SAP.
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Kim, Jong-Ho
ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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