Hierarchical packing of racemic metallosupramolecular cages with Ni(II)-based triple-stranded helicate building blocks
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Nguyen, Thanh Nhan | - |
dc.contributor.author | Nguyen, Anh Ngoc | - |
dc.contributor.author | Tran, Ngoc Minh | - |
dc.contributor.author | Park, In-Hyeok | - |
dc.contributor.author | Yoo, Hyojong | - |
dc.date.accessioned | 2023-07-05T05:45:00Z | - |
dc.date.available | 2023-07-05T05:45:00Z | - |
dc.date.issued | 2023-05 | - |
dc.identifier.issn | 2052-2525 | - |
dc.identifier.issn | 2052-2525 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/113294 | - |
dc.description.abstract | Three novel hierarchical Ni-based metallosupramolecular cages were constructed from nickel ions, pyridine dicarboxylates and isophthalate derivative ligands (the substituents on C5 of isophthalate are methyl, tert-butyl and bromo groups). In every cage, two multinuclear nickel clusters, assembled from four nickel atoms and three pyridine dicarboxylate ligands, are interlinked by three isophthalate-derivative ligands to form a nickel-based triple-stranded helicate (TSH), which then becomes the supramolecular building block for the fabrication of a metallocage. Six homochiral TSH supramolecular building blocks, either left (M)-handed or right (P)-handed, are connected by four linking nickel atoms to generate M-6 and P-6 discrete racemic cage molecules (M-6 - cage with six M-TSHs; P-6 - cage with six P-TSHs). The crystal packing of the racemic cages was characterized by single-crystal X-ray diffraction. An additional cobalt-based molecular cage with 5-methylisophthalate bridging ligands was synthesized for host-guest interaction studies. The methyl groups in Co- and Ni-TSH can act as guest units to be accommodated in the cone-shaped metal clusters (host) of an adjacent cage. | - |
dc.format.extent | 8 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | International Union of Crystallography | - |
dc.title | Hierarchical packing of racemic metallosupramolecular cages with Ni(II)-based triple-stranded helicate building blocks | - |
dc.type | Article | - |
dc.publisher.location | 영국 | - |
dc.identifier.doi | 10.1107/S2052252523002385 | - |
dc.identifier.scopusid | 2-s2.0-85159205226 | - |
dc.identifier.wosid | 000980807600010 | - |
dc.identifier.bibliographicCitation | IUCrJ, v.10, no.Pt 3, pp 321 - 328 | - |
dc.citation.title | IUCrJ | - |
dc.citation.volume | 10 | - |
dc.citation.number | Pt 3 | - |
dc.citation.startPage | 321 | - |
dc.citation.endPage | 328 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | Y | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Crystallography | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Crystallography | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | HOST-GUEST CHEMISTRY | - |
dc.subject.keywordPlus | COORDINATION-DRIVEN | - |
dc.subject.keywordPlus | SOLVENT | - |
dc.subject.keywordPlus | DISCRETE | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | INTERCONVERSION | - |
dc.subject.keywordPlus | TRANSFORMATION | - |
dc.subject.keywordPlus | NANOCAGES | - |
dc.subject.keywordPlus | STRATEGY | - |
dc.subject.keywordPlus | CHAIN | - |
dc.subject.keywordAuthor | nickel-based racemic cages | - |
dc.subject.keywordAuthor | high-order assemblies | - |
dc.subject.keywordAuthor | triple-stranded helicates | - |
dc.subject.keywordAuthor | supramolecular building blocks | - |
dc.subject.keywordAuthor | metallocavitands | - |
dc.subject.keywordAuthor | metallosupramolecular cages | - |
dc.identifier.url | https://journals.iucr.org/m/issues/2023/03/00/yc5042/index.html | - |
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