A Cobalt Supramolecular Triple-Stranded Helicate-based Discrete Molecular Cage
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Mai, Hien Duy | - |
dc.contributor.author | Kang, Philjae | - |
dc.contributor.author | Kim, Jin Kyung | - |
dc.contributor.author | Yoo, Hyojong | - |
dc.date.accessioned | 2021-06-22T15:22:08Z | - |
dc.date.available | 2021-06-22T15:22:08Z | - |
dc.date.created | 2021-01-22 | - |
dc.date.issued | 2017-03 | - |
dc.identifier.issn | 2045-2322 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/11564 | - |
dc.description.abstract | We report a strategy to achieve a discrete cage molecule featuring a high level of structural hierarchy through a multiple-assembly process. A cobalt (Co) supramolecular triple-stranded helicate (Co-TSH)-based discrete molecular cage (1) is successfully synthesized and fully characterized. The solid-state structure of 1 shows that it is composed of six triple-stranded helicates interconnected by four linking cobalt species. This is an unusual example of a highly symmetric cage architecture resulting from the coordination-driven assembly of metallosupramolecular modules. The molecular cage 1 shows much higher CO2 uptake properties and selectivity compared with the separate supramolecular modules (Co-TSH, complex 2) and other molecular platforms. © 2017 The Author(s). | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | Nature Publishing Group | - |
dc.title | A Cobalt Supramolecular Triple-Stranded Helicate-based Discrete Molecular Cage | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Yoo, Hyojong | - |
dc.identifier.doi | 10.1038/srep43448 | - |
dc.identifier.scopusid | 2-s2.0-85014766396 | - |
dc.identifier.wosid | 000395425500001 | - |
dc.identifier.bibliographicCitation | Scientific Reports, v.7, pp.1 - 7 | - |
dc.relation.isPartOf | Scientific Reports | - |
dc.citation.title | Scientific Reports | - |
dc.citation.volume | 7 | - |
dc.citation.startPage | 1 | - |
dc.citation.endPage | 7 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | Y | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalWebOfScienceCategory | Multidisciplinary Sciences | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORKS | - |
dc.subject.keywordPlus | CARBON-DIOXIDE CAPTURE | - |
dc.subject.keywordPlus | BUILDING-BLOCKS | - |
dc.subject.keywordPlus | COORDINATION CAGE | - |
dc.subject.keywordPlus | RETICULAR SYNTHESIS | - |
dc.subject.keywordPlus | OXIDATION-STATE | - |
dc.subject.keywordPlus | GUEST-BINDING | - |
dc.subject.keywordPlus | POLYHEDRA | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | CO2 | - |
dc.identifier.url | https://www.nature.com/articles/srep43448 | - |
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