Reoxidation Phenomena of Liquid Steel in Secondary Refining and Continuous Casting Processes: A Review

Abstract

This review article reports the critical issue of reoxidation in clean steel production during secondary refining and continuous casting processes. Reoxidation presents substantial challenges to process stability and final product quality. Various sources of reoxidation, including exposure to oxidizing gases, reducible oxides in slag and refractories, and the presence of ferroalloys are explored. Fundamental reactions and their consequences, such as changes in steel composition, inclusion composition/morphology, and the formation of reaction products at the interface between liquid steel and refractory materials, are reviewed. High oxygen partial pressure on the refractory side is identified as a significant factor, particularly in tundish and continuous casting processes. To address reoxidation effectively, the review discusses modeling approaches like computational fluid dynamics and thermodynamic/kinetic modeling. In the industrial context, reoxidation in the tundish is mainly attributed to open-eye formation in the tundish flux and reducible oxides like SiO2 in an insulating cover powder, for example, rice hust ash. Maintaining precise tundish flux control is crucial for steel cleanliness. In conclusion, this review highlights the multifaceted nature of reoxidation challenges in clean steel production. A comprehensive understanding of reoxidation mechanisms and the implementation of effective strategies are essential for achieving cleaner steel production. © 2023 Wiley-VCH GmbH.