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Site-Specific Synthesis of Carbazole Derivatives through Aryl Homocoupling and Amination
- Issue Date
- Mar-2020
- Publisher
- Georg Thieme Verlag
- Keywords
- N-acetylation; aryl homocoupling; Ullmann coupling reaction; Tauber carbazole synthesis; intramolecular amination
- Citation
- Synthesis, v.52, no.6, pp 917 - 927
- Pages
- 11
- Indexed
- SCIE
SCOPUS
- Journal Title
- Synthesis
- Volume
- 52
- Number
- 6
- Start Page
- 917
- End Page
- 927
- ISSN
- 0039-7881
1437-210X
- Abstract
- We synthesized various carbazoles from anilines through a three-step process with good overall yields (up to 48%). This process comprises N-acetylation, copper(0)-mediated Ullmann homocoupling, and acid-mediated intramolecular amination. It permits various functional-groups on the substrate. Scale-up of the developed three-step synthetic route to carbazoles was also demonstrated.
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Related Researcher
- Rhee, Hak june
- ERICA 공학대학 (ERICA 에너지바이오학과)