Preparation of Novel Quaternary Plastomers with Extremely Low Glass Transition Temperature
- Authors
- 김진훈; 김정수; 김민성; 김기범; 양홍주; 하성철; 장영욱; 김동현
- Issue Date
- Sep-2016
- Publisher
- 한국고무학회
- Keywords
- metallocene catalyst; plastomers; glass transition temperature; quaternary polymer
- Citation
- 엘라스토머 및 콤포지트, v.51, no.3, pp.188 - 194
- Indexed
- KCI
- Journal Title
- 엘라스토머 및 콤포지트
- Volume
- 51
- Number
- 3
- Start Page
- 188
- End Page
- 194
- URI
- https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/15056
- DOI
- 10.7473/EC.2016.51.3.188
- ISSN
- 2092-9676
- Abstract
- In this study, novel quaternary plastomers consisting of ethylene, 1-hexene, high α-olefin, and divinylbenzene were prepared using Zr metallocene catalyst, borate type cocatalyst, and tri-isobutylaluminium. The molar ratio changes of 1-hexene and high α-olefin (1-octene, 1-decene, and 1-dodecene) had an effect on the properties of the quaternary plastomers.
The structure of the quaternary plastomers was characterized using 1H NMR. Molecular weight properties, crystallinity, and thermal properties of the plastomers were determined by GPC, WAXS, and DMA, respectively. Compared with the terpolymers prepared in our previous study, molecular weight and molecular weight distribution of the quaternary polymers were very similar, whereas glass transition temperature (Tg) was very low. Also, hardness and tensile properties of the quaternary plastomers were measured.
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