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Selective Synthesis of Ruthenium(II) Metalla[2]Catenane via Solvent and Guest-Dependent Self-Assembly
- Issue Date
- Apr-2015
- Publisher
- American Chemical Society
- Citation
- Journal of the American Chemical Society, v.137, no.14, pp 4674 - 4677
- Pages
- 4
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- Journal of the American Chemical Society
- Volume
- 137
- Number
- 14
- Start Page
- 4674
- End Page
- 4677
- ISSN
- 0002-7863
1520-5126
- Abstract
- The coordination-driven self-assembly of an anthracene-functionalized ditopic pyridyl donor and a tetracene-based dinuclear Ru(II) acceptor resulted in an interlocked metalla[2]catenane, [M2L2](2), in methanol and a corresponding monorectangle, [M2L2], in nitromethane. Subsequently, guest template, solvent, and concentration effects allowed the self-assembly to be reversibly fine-tuned among monorectangle and catenane structures.
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